Biocatalytic reduction of alkenes in micro-aqueous organic solvent catalysed by an immobilised ene reductase

Catal. Sci. Technol., 2023, 13,5530-5535
DOI: 10.1039/D3CY00541K, Communication
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rocio Villa, Claudia Ferrer-Carbonell, Caroline E. Paul
Immobilised TsOYE on Celite carrier catalyses the bioreduction of activated alkenes in pure organic solvent, providing full conversion to (chiral) products.
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Two-dimensional (2D) layered double metal cyanides as alternative catalysts for CO2/propylene oxide copolymerization

Catal. Sci. Technol., 2023, 13,5214-5226
DOI: 10.1039/D3CY00753G, Paper
Guillermo Penche, María P. González-Marcos, Juan R. González-Velasco, Cyler W. Vos, Christopher M. Kozak
Layered 2D DMC complexes were first catalysts for green copolymerization of CO2 and PO to produce biodegradable and biocompatible polymers. The Co[Ni(CN)4] complex showed promising potential in this process and was further evaluated.
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Dynamic hydrogen bubbling templated AgSn@SnOx electrocatalyst for selective electrochemical CO2 reduction: adjusting the binding energy of the HCOO* intermediate

Catal. Sci. Technol., 2023, 13,5175-5179
DOI: 10.1039/D3CY00939D, Communication
Hisham G. El-Aqapa, Ibrahim M. Badawy, Ghada E. Khedr, Ahmed M. Agour, Doha M. Sayed, Manar M. Taha, Nageh K. Allam
Core–shell AgSn@SnOx catalysts demonstrated selective CO2RR towards HCOOH with a faradaic efficiency of 96 ± 4.9% and partial current density of −10.46 ± 0.35 mA cm−2 by adjusting the binding energy of the HCOO* intermediate.
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Organic additive for the selective C2-product formation on Cu(100): a density functional theory mechanistic study

Catal. Sci. Technol., 2023, 13,5365-5373
DOI: 10.1039/D3CY00857F, Paper
Amitabha Das, Shyama Charan Mandal, Biswarup Pathak
Electrochemical CO2 reduction is a promising approach to increase the chemical feedstock of energetically valuable products, especially ethylene and ethanol.
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Tuning catalytic activity with steric and electron-withdrawing effects of a porphyrin substituent

Catal. Sci. Technol., 2023, 13,5280-5289
DOI: 10.1039/D3CY00758H, Paper
Lulu Jiang, Yosuke Imanaka, Hiroshi Fujii
The reactivity, spectroscopic, and kinetic studies of the catalytic reactions showed that the catalytic activity is determined by the balance of the rates of the formation, reaction, and decomposition reactions of the reactive intermediate.
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Active vanadium(IV) species synthesized at low-temperature facilitate excellent performance in low-temperature NOx-catalytic removal

Catal. Sci. Technol., 2023, 13,5197-5204
DOI: 10.1039/D3CY00718A, Paper
Liwei Sun, Peng Liu, Jianheng Xu, Kaijie Liu, Zeshu Zhang, Yibo Zhang, Xiangguang Yang
V4+ species in a series of bulk vanadium oxide catalysts is more conducive to NH3 and O2 activation.
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Unlocking the potential of catalysts in thermochemical energy conversion processes

Catal. Sci. Technol., 2023, 13,5632-5653
DOI: 10.1039/D3CY00848G, Paper
Avinash Alagumalai, Balaji Devarajan, Hua Song
Catalysis is indeed an essential component of many energy-related processes and is likely to become even more critical as we transition towards more sustainable and low-carbon energy systems.
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Efficient additive-free formic acid dehydrogenation with a NNN–ruthenium complex

Catal. Sci. Technol., 2023, 13,5625-5631
DOI: 10.1039/D3CY00512G, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pascal Knörr, Nicolas Lentz, Martin Albrecht
A new phosphine-free N,N,N-coordinated ruthenium complex featuring a pyridylidene amine (PYE) ligand catalyzes the dehydrogenation of formic acid with high activity; mechanistic studies reveal a critical role of the central N-donor of the NNN ligand.
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