Spatial Well-defined Metal-Corrole-Based Covalent Organic Polymers toward Remarkably Enhanced Multipurpose Electrocatalysis and High-Performance Zinc-Air Batteries

Catal. Sci. Technol., 2023, Accepted Manuscript
DOI: 10.1039/D3CY00802A, Paper
Yanfang Yao, Zhen-Yu Huang, Wan-Yue Xie, Si-Jing Huang, Zhengyan Liu, Gang Yang, Jianshan Ye, Hai-Yang Liu, Xinyan Xiao
Incorporating the intrinsic catalytic activity of discrete molecular catalysts into covalent frameworks often enables improved electrocatalytic performance. Metallocorroles that represent a burgeoning class of attractive metal-complexes from the porphyrinoid family...
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Modulating Active Oxygen Species on α-MnO2 with K and Pb for SCR of NO at Low Temperatures

Catal. Sci. Technol., 2023, Accepted Manuscript
DOI: 10.1039/D3CY01068F, Paper
Gang Yang, Xiang Luo, Shuai Liu, Cheng-Gong Sun, Tao Wu
Low temperature (LT) selective catalytic reduction (SCR) of NOx has been a research hotspot. However, the roles of oxygen vacancies and active oxygen species in LT SCR process are still...
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Tuning the Catalytic Performance of CaSnO3 by Developing S-Scheme P-N Heterojunction through Ag6Si2O7 Doping

Catal. Sci. Technol., 2023, Accepted Manuscript
DOI: 10.1039/D3CY01151H, Paper
Navid Hussain Shah, Muhammad Abbas, Muhammad Qasim, Muhammad Sulaman, Muhammad Imran, Sohail Azmat, Yanyan Cui, Yaling Wang
Perovskites especially alkaline earth stannates, have drawn enormous interest from the research community owing to their low chemical toxicity, environmental friendliness, excellent optical properties, and better thermal and chemical stabilities....
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Construction of core-shell MOF@COF hybrids with Z-scheme heterojunction for efficient visible light photocatalysis

Catal. Sci. Technol., 2023, Accepted Manuscript
DOI: 10.1039/D3CY00869J, Paper
Jun Pang, Weijie Chen, Jintao Hu, Jie Cheng, Mingqiang Tang, Zewei Liu, Rong Tan
Metal-organic frameworks (MOFs) have emerged as promising photocatalysts due to their tunable architectures and semiconductor-like behavior. However, their photocatalytic efficiency is often hampered by suboptimal light utilization and fast charge...
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Tuning the active sites and optimizing the d-spacing value in CoFe-LDH by ex situ intercalation of guest anions: an innovative electrocatalyst for overall water splitting reaction

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00859B, Paper
Sreenivasan Nagappan, Arun Karmakar, Ragunath Madhu, Hariharan N. Dhandapani, Suprobhat Singha Roy, Subrata Kundu
A facile strategy of ex situ guest anion incorporation into CoFe-LDH has been developed, in which the guest anion with the optimized concentration greatly enhances the OER, HER and total water splitting performance of the CoFe-LDH.
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Natural alternative heme-environments allow efficient peroxygenase activity by cytochrome P450 monooxygenases

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY01207G, Paper
Open Access Open Access
Ana C. Ebrecht, Martha S. Smit, Diederik J. Opperman
Mild oxyfunctionalization reactions driven by hydrogen peroxide using cytochrome P450 monooxygenases with alternative heme environments.
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Methane monooxygenases; physiology, biochemistry and structure

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00737E, Review Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yasuyoshi Sakai, Hiroya Yurimoto, Seigo Shima
Methane monooxygenases (MMOs) are potential biocatalysts for industrial methanol production from methane. We summarize recent structural and biochemical studies of pMMO and discuss the future directions to develop efficient and robust biocatalysts.
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Carbon-supported Co/Co3O4 hybrid catalyst: an efficient non-noble metal catalyst for the hydrodeoxygenation of vanillin

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00971H, Paper
Zhihua Zhu, Chaochong Zhang, Peng Zhou, Bo Han, Zehui Zhang, Bing Liu
Developing Co-based catalysts with high efficiency and low cost is significant for the efficient hydrodeoxygenation of biomass-derived vanillin to 2-methoxy-4-methylphenol (MMP).
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Enhancing the performance for palladium catalysed tert-butyl hydroperoxide-mediated Wacker-type oxidation of alkenes

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY01046E, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthew N. Blair, Meadhbh Murray-Williams, Calum Maguire, Clare L. Brown, Qun Cao, Hongxin Chai, Yitong Li, Róisín L. O'Hagan, Paul Dingwall, Panagiotis Manesiotis, Catherine L. Lyall, John P. Lowe, Ulrich Hintermair, Peter C. Knipe, Mark J. Muldoon
This work examines the palladium(II) catalysed oxidation of terminal alkenes to their corresponding methyl ketones using tert-butyl hydroperoxide (TBHP) as the oxidant.
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Computational modeling guided design of metal–organic frameworks for photocatalysis – a mini review

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00862B, Minireview
Sheng Yu, Qiaomin Wang, Jinglei Wang, Cong Fang, Yuanzhe Li, Jiankai Ge, Baizeng Fang
Metal–organic frameworks (MOFs) are porous materials used in photocatalysis. Their structure is optimized using computational modeling. This review emphasizes the role of computational design in enhancing MOF efficiency.
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