Direct annulation between glycine derivatives and thiiranes through photoredox/iron cooperative catalysis

Chem. Commun., 2023, Advance Article
DOI: 10.1039/D3CC04580C, Communication
Shutao Wang, Yuan Gao, Yansong Hu, Jintao Zhou, Zhidang Chen, Zhao Liu, Yuan Zhang
A visible-light-induced aerobic oxidative [2+3] cycloaddition reaction between glycine derivatives and thiiranes is achieved via a cooperative photoredox catalysis and iron catalysis.
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Orthogonal Chain Collapse in Stimuli-responsive Di-block Polymers leading to Self-sorted Nanostructures

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04029A, Communication
Chirag Miglani, Maqsuma Banoo, Debasish Nath, Jahanvi Ralhan, Soma Sil, Jojo P Joseph, Santanu Kumar Pal, Ujjal Gautam, Asish Pal
Self-assembly of molecular building blocks to form discrete compartments with orthogonal functions has its relevance to emulate biological cells. Herein, we design amphiphilic di-block copolymers (P-b-F and P-b-C) tethered with...
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Trans-Cleavage of CRISPR-Cas12a-Aptamer System for One-Step Antigen Detection

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04532C, Communication
Hongxuan Fan, Shihua Luo, Ying Zhu, Jiye Shi, Fangfei Yin, Jiang Li
Rapid detection of prostate-specific antigen (PSA) is pivotal for the early screening of prostate cancer (PCa). Here, we devise a one-step, amplification-free fluorescent detection strategy for PSA, employing the trans-cleavage...
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Enolate addition to bicyclobutanes enables expedient access to 2-oxo-bicyclohexane scaffolds

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04234K, Communication
Kyla Woelk, Kushal Dhake, Nathan D. Schley, David Leitch
We report the synthesis of 2-oxo-bicyclo[2.1.1]hexanes (2-oxo-BCHs) from bicyclobutanes (BCBs) and readily available enolate precursors. We propose this reaction proceeds via initial enolate addition to the bicyclobutane, followed by an...
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Regulating stereoselectivity of medium-chain dehydrogenase/reductase by creating additional active pocket accommodating prochiral heterocyclic ketones

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04361D, Communication
Lei Qin, Xin Su, Jun Wang, Lunjie Wu, Man Zou, Jie Gu, Yan Xu, Yao Nie
Medium chain dehydrogenase/reductase (MDR) is a robust catalyst for the asymmetric synthesis of chiral heterocyclic alcohols, essential building blocks in pharmaceuticals. However, the regulatory mechanism of stereoselective complementary reduction of...
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Visible light-mediated C(sp3)-H bond functionalization inside an all-organic nanocavity

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC03987K, Communication
Debojyoti Roy, Sunandita Paul, Jyotishman Dasgupta
Ultrafast C-H bond activation in confinement using visible light will enable engineering chemical reactions with extraordinary speed and selectivity. To provide a transition metal-free route here we demonstrate C-H bond...
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A Triad Molecular Conductor: Simultaneous Control of Charge and Molecular Arrangements

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC03198E, Communication
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Naoya kinoshita, Atsuya Maruyama, Takashi Shirahata, Toshio Naito, Yohji Misaki
Molecular and charge arrangements in the solid state were controlled by a new building block: a triad molecule. Owing to the appropriate flexibilities in both molecular structure and electron distribution...
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Ultrafast Charge Transfer in Metal-Free H2O2 Photoproduction by Anhydride Modified g-C3N4

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC03807F, Communication
YING XIE, Jingjing Liu, Guanxiong Wang, Qiushi Hu, Xihan Chen
As a low-cost, low toxicity and metal-free catalyst with strong light absorption, graphitic carbon nitride (g-C3N4)-based materials have gained wide attention for efficient H2O2 photocatalysis. However, further investigation regarding the...
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Nitrogen-doped Fe7S8 as Highly Efficient Electrocatalysts for the Hydrogen Evolution Reaction

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC03376G, Communication
Jian Ye, Shuwen Niu, LeiJie Zhang, Gongming Wang, Junfa Zhu
The high unoccupied d band energy of FeS2 basically results in weak orbital coupling with water molecules, consequently leading to sluggish water dissociation kinetics. Herein, we demonstrate that the N-induced...
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Electrochemiluminescence of dimethylaminonaphthalene-oxazaborine donor–acceptor luminophores

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC03892K, Communication
Kyoung-Rok Kim, Jiwoo Kim, Jinrok Oh, Joohoon Kim, Jong-In Hong
Donor-acceptor (D-A) type molecules with a skeleton consisting of a dimethylaminonaphthalene donor and an oxazaborine acceptor were designed as efficient electrochemiluminescence (ECL) luminophores with tunable intramolecular charge transfer (ICT). The...
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