NHC-Catalyzed Radical Acylation of Cycloalkyl Silyl Peroxides to Access 1,6-, 1,7-, and 1,8-Diketones

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04765B, Communication
Chaolei Liu, Jingyi Wang, Xinlong Liu, Jie Feng, Ding Du
An unprecedented N-heterocyclic carbene (NHC)-catalyzed radical acylation of cycloalkyl silyl peroxides was developed using readily available aldehydes as the acylating agents. This protocol provides an exceptionally useful method for the...
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Electrochemical deoxygenative homo-couplings of aromatic aldehydes

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC03346E, Communication
Xiaoqian Zhao, Meng Li, Kunhui Sun, Zhimin Xu, Lifang Tian, Yahui Wang
An electrochemical deoxygenative homo-coupling of aromatic aldehydes is achieved to selectively access bibenzyl and stilbene derivatives. The protocol allows the homo-coupling of aldehydes to occur after single-electron-reduction at the cathode....
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Selective and Benign Alkylation of Sulfido-Oxo Stannate Clusters with Propyl, Pentyl, or Hexyl Substituents

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC03525E, Communication
Gina Stuhrmann, Jannik Schneider, Kilian Schmidt, Stefanie Susanne Dehnen
Chalcogenido metalate compounds that are based on tetrahedral clusters have been extensively studied in recent years due to their rich structural chemistry1 and uncommon chemical and physical properties.2 Recently it...
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Advances in circularly polarized luminescence materials based on chiral macrocycles

Chem. Commun., 2023, Advance Article
DOI: 10.1039/D3CC04187E, Feature Article
Jia-Qi Wang, Xiao-Ni Han, Ying Han, Chuan-Feng Chen
This review comprehensively summarizes circularly polarized luminescence materials from chiral macrocycles, especially chiral macrocyclic hosts and their derivatives.
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Ferrimagnetic and spin glass behaviour in the SrMn2+3Ti4+14M3+4O38 (M = Ti and Fe) synthetic crichtonites.

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04336C, Communication
Open Access Open Access
Jose Luis Rosas-Huerta, Ruiqi Chen, Clemens Ritter, Oleg I. Siidra, Marie Colmont, Angel M. Arevalo-Lopez
The novel SrMn2+3Ti4+14M3+4O38 (M = Ti and Fe) compounds with the crichtonite-type structure are reported herein. M = Ti shows a ferrimagnetic behavior at TN = 15 K, while M...
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Impact of Subtle Intermolecular Interactions on Structure and Dynamics of Multicomponent Supramolecular Polymers

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04567F, Communication
Job N.S. Hanssen, Shikha Dhiman
Multicomponent supramolecular polymers offer versatile dynamic and functional properties, yet the influence of monomer chemical structures on their structure-dynamics-function relationship remains unclear. This study investigates the subtle variations in monomer...
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A Gemini basic ionic liquid and functionalized cellulose nanocrystal-based mixed matrix membrane for CO2/N2 separation

Chem. Commun., 2023, Advance Article
DOI: 10.1039/D3CC03628F, Communication
Prarthana Bora, Chinmoy Bhuyan, Parashmoni Rajguru, Swapnali Hazarika
An energy efficient and durable solution for high CO2 emission has been introduced via the development of an ionic liquid and amine channelized mixed matrix membrane with high CO2 permeance and CO2/N2 selectivity.
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Insight into Active Sites of Nitrogen-doped Carbon Catalyst by Stochastic Collision Electrochemistry

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04505F, Communication
Jianwei Zong, Wenjie Wu, Lanqun Mao, Ping Yu
Identifying the active sites of electrocatalysts is conducive to catalyst design. However, determining the specific active sites of catalysts is still a challenge. Herein, we demonstrate that stochastic collision electrochemistry...
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High-entropy wire-on-sheet nanoarray catalyst with boosted pre-oxidation for efficient oxygen evolution reaction

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04684B, Communication
Min Hao, Jing Chen, Zimeng Liu, Xiaoning Sun, Shan-Shan Liu, Fengcai Lei, Xu Sun, Junfeng Xie, Bo Tang
Herein, a septenary NiCoZnFeCuMnCe hydroxide nanoarray catalyst with unique wire-on-sheet morphology and high-entropy feature was fabricated, which exhibits boosted pre-oxidation behavior and synergistically enhanced catalytic activity and durability towards the...
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Phosphine-catalyzed Formal Buchner [6+1] Annulation: De Novo Construction of Cycloheptatrienes

Chem. Commun., 2023, Accepted Manuscript
DOI: 10.1039/D3CC04905A, Communication
Jingxiong Lai, You Huang
An unprecedented phosphine-catalyzed formal Buchner [6+1] annulation of a newly designed allenoate has been developed, providing a series of cycloheptatriene derivatives in moderate to good yields (up to 99%). This...
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