Controllable synthesis of star-shaped FeCoMnOx nanocrystals and their self-assembly into superlattices with low-packing densities

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00332B, Communication
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhe Xia, Yutong Gao, Qingfu Cai, Yajun Wang, Dong Yang, Tongtao Li, Angang Dong
Monodisperse, star-shaped FeCoMnOx nanocrystals with tunable concavity were synthesized and employed as building blocks for self-assembly at the air-liquid interface, resulting in two types of two-dimensional superlattices with low packing densities.
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Amide-to-chloroalkene substitution for overcoming intramolecular acyl transfer challenges in hexapeptidic neuromedin U receptor 2 agonists

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D3CC06197C, Communication
Tetsuo Narumi, Daichi Toyama, Junko Fujimoto, Ryuji Kyan, Kohei Sato, Kenji Mori, James T. Pearson, Nobuyuki Mase, Kentaro Takayama
Amide-to-chloroalkene substitution in CPN-116 increases stability and maintains hNMUR2 agonistic activity and selectivity, overcoming intramolecular acyl transfer on the Dap residue.
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Synthesis of sydnonimines from sydnones and their use for bioorthogonal release of isocyanates in cells

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00490F, Communication
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Judith Baudet, Emilie Lesur, Maxime Ribéraud, Arnaud Chevalier, Timothée D’Anfray, Pierre Thuéry, Davide Audisio, Frédéric Taran
A new synthetic route to sydnonimines allows the preparation of probes to release isocyanates inside living cells.
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Anti-proliferative, -migratory and -clonogenic effects of long-lasting nitric oxide release in HepG2 cells

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00232F, Communication
Rakhi Bormon, Ekta Srivastava, Rafat Ali, Prerna Singh, Ashok Kumar, Sandeep Verma
We have synthesized 6,9-disubstituted purines that exhibit sustained release of nitric oxide in the presence of glutathione, displaying significant anticancer properties in HepG2 cells.
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Building (001) oriented FAPbI3 films for high-performing perovskite solar cells

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00212A, Communication
Yingke Ren, Hongyang Fu, Yingjie Sun, Zhaoqian Li, Xinge Guo, Xingtao An
The solution processed FAPbI3 perovskite usually suffers from chaotic orientations.
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Remote control of anion binding by CH-based receptors

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D3CC06038A, Communication
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paulina Jurek, Marek P. Szymański, Agnieszka Szumna
We show that the substitution of tetra(benzimidazole)resorcin[4]arenes with electron withdrawing groups on the upper rim enhances anion binding at the opposite edge by more than three orders of magnitude.
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Columnar liquid crystals based on antiaromatic expanded porphyrins

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D3CC05414D, Communication
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Duong D. Nguyen, Jorge Labella, Juan Laforga-Martín, César L. Folcia, Josu Ortega, Tomás Torres, Teresa Sierra, Jonathan L. Sessler
Antiaromatic expanded porphyrins designed to self-assemble into columnar liquid crystalline (LC) structures are synthesized and characterized by multiple techniques. The substituents were found to play a crucial role in modulating the LC behaviour.
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Synthesis of polyvinylethylene glycols (PVEGs) via polyetherification of vinylethylene carbonate by synergistic catalysis

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D3CC05580A, Communication
Open Access Open Access
Fan Yang, Minghang Wang, Yong Jian Zhang
A novel type of polyether called polyvinylethylene glycols (PVEGs) is prepared by effective and controllable polyetherification via synergistic catalysis.
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Light-activated g-C3N4 photoelectrodes with a selective molecular sieve for in vivo quantification of oxygen levels in the living mouse brain

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00246F, Communication
Yifan Da, Qi Sun, Limin Zhang, Yang Tian
(A) Schematic illustration of the photoelectrode construction for in vivo detection in the mouse brain. (B) Schematic illustration of the mechanism for the detection of O2 by the developed photoelectrode.
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One-pot synthesis of azabora[6]helicene by a Schiff base forming reaction

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00168K, Communication
Yuto Kage, Yuchuan Jiang, Namiki Minakuchi, Shigeki Mori, Soji Shimizu
Azabora[6]helicene as a new heterohelicene analogue was synthesized by a one-pot reaction of commercially available 2,6-diaminopyridine and benzo[c,d]indole-2(1H)-one and subsequent boron coordination.
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