Category Archives: RSC – CrystEngComm

Highly varied reaction cavities within a single molecular crystal

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CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00714F, Paper
Michael R. Carr, Matthew Kochert, Wathsala L. I. Waduge, Gregory J. Deye, Kenneth W. Olsen, Jacob W. Ciszek
The various facets of a tetracene single crystal present highly varied reaction cavities at its surface, finally allowing for a systemic study of the cavities, which are critical to the reactivity in the solid phase.
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Facile fabrication and characterization of rare earth complexes based on Keggin-type polyoxometalate with highly efficient activity for photocatalytic degradation of MO

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CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00746D, Paper
Ying-Yu Li, Guan-Yu Jin, Zhi-Qiang Wang, Cong Hu, Xue-Dong Wang, Jian-Ming Liu, Min Liu, Hong-Liang Han, Zhong-Feng Li, Qiong-Hua Jin
Rare earth complexes based on Keggin-type polyoxometalate for photocatalytic degradation of MO. The degradation rate reached more than 95% within 15 min.
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Anisotropy of growth hillocks on KDP crystal (101) faces observed by in situ interferometry

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CrystEngComm, 2023, 25,5506-5512
DOI: 10.1039/D3CE00504F, Paper
Xianglin Li, Shenglai Wang, Weidong Li, Hui Liu, Longyun Xu, Liyuan Zhang
In situ interference and AFM were used to study the effect of supersaturation and temperature on the growth rates and slopes of KDP crystal (101) faces.
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Ligand competition on uranyl ion: further examples of zwitterionic vs. anionic carboxylate coordination

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CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00845B, Paper
Open Access Open Access
Sotaro Kusumoto, Youssef Atoini, Yoshihiro Koide, Shinya Hayami, Yang Kim, Jack Harrowfield, Pierre Thuéry
Four mixed-ligand uranyl ion complexes with anionic and zwitterionic carboxylates illustrate different modes of association of these ligands and give some clues about their respective donor strength.
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A co-crystal of heterobicyclic isomers as a product of the cyclocondensation reaction of 3,4-diaminofurazan with diethyl-2-oxosuccinate

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CrystEngComm, 2023, 25,5413-5419
DOI: 10.1039/D3CE00769C, Paper
Galina V. Romanenko, Sergey V. Fokin, Svyatoslav E. Tolstikov, Gleb A. Letyagin, Victor I. Ovcharenko, Kirill V. Strizhenko, Aleksei B. Sheremetev
Using SC XRD, it was proved that the cyclocondensation of 3,4-diaminofurazan with diethyl-2-oxosuccinate gives two products, being structural isomers – derivatives of furazano[3,4-b]pyrazin-6-one (2) and furazano[3,4-b][1,4]diazepin-7-one (6).
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Spontaneous resolution of two chiral metal–organic frameworks through local geometric and lattice frustration effects

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CrystEngComm, 2023, 25,5428-5435
DOI: 10.1039/D3CE00784G, Paper
Hunter J. Windsor, Cameron J. Kepert, Lauren K. Macreadie
Two chiral metal–organic frameworks that are differentiated by their Cd-centred helical twists are prepared by spontaneous chiral resolution from rigid, aliphatic, and achiral precursors.
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Impact of substituent’s position on the DSSC performances of new 1,1′-bis-(diphenylphosphino)ferrocene appended nickel(II) methoxy cyanodithiolates

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CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00621B, Paper
Devyani Srivastava, Aparna Kushwaha, Gabriele Kociok-Köhn, Suresh W. Gosavi, Ratna Chauhan, Muthupandian Ashokkumar, Abhinav Kumar, Mohd. Muddassir
New dppf appended Ni(II) complexes with isomeric dithiolate synthesized and used as sensitizers in DSSC.
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2D graphitic-like gallium nitride and other structural selectivity in confinement at the graphene/SiC interface

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CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00515A, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gianfranco Sfuncia, Giuseppe Nicotra, Filippo Giannazzo, Béla Pécz, Gueorgui Kostov Gueorguiev, Anelia Kakanakova-Georgieva
An atomic resolution image of an intercalated structure at a graphene/SiC interface along the growth direction which is determined as a buckled GaN monolayer at the immediate interface with an underlying SiC substrate and ultrathin Ga2O3 on top.
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Realizing luminescent from cuprous iodide complexes with high quantum yields by introducing planar aromatic groups and modification with halogen atoms on the ligand

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CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00815K, Paper
Abraham Mensah, Wei-Min Chen, Ennin Vendish Kweku, Peng-Lai Liu, Juan-Juan Shao, Fang-Ming Wang, Li-Zhuang Chen
Five novel AIO-structured cuprous iodide hybrid materials are prepared by introducing planar aromatic groups on the ligand DABCO. All the complexes have good stability, solubility, and high emission quantum yields (QYs) ranging from 70.3–95.3%.
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