Hexnuclear, octanuclear, dodecanuclear, and hexadecnuclear polyoxomolybdenum(V)-based porous materials for selective adsorption of gases

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00736G, Paper
Rong-Yan Lin, Ru-Dan Dai, Xin Dong, Zhao-Hui Zhou
As the pH values decreased, triazole derivative assisted hexa-, octa-, hexadec- and dodeca-polynuclear molybdate-based porous complexes 1–4 are constructed successively. 1–4 have a good adsorption effect on O2 and CO2 respectively.
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Six novel multicomponent systems of theobromine with carboxylic acids: crystallographic structures, solubility determination and DFT calculations

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00762F, Paper
Xin-Yue Yuan, Yan Cheng, Jun Liu, Qi-Lei Sun, Fu-Min Xue
Cocrystals of theobromine with carboxylic acids prepared by ball milling and solution method: crystallographic structures and solubility determination.
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Microdialysis on-chip crystallization of soluble and membrane proteins with the MicroCrys platform and in situ X-ray diffraction case studies

CrystEngComm, 2023, 25,5513-5523
DOI: 10.1039/D3CE00466J, Paper
Sofia Jaho, Yoann Sallaz-Damaz, Monika Budayova-Spano
The MicroCrys platform was developed to automate on-chip dialysis crystallization of proteins via chemical composition and temperature control, facilitating the optimization of crystallization conditions and the exploration of protein phase diagrams.
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Chemical vapour synthesis of carbon nano-onions filled with high-spin ferromagnetic γ-Fe50Ni50 nanocrystals: a structural and magnetic investigation

CrystEngComm, 2023, 25,5382-5386
DOI: 10.1039/D3CE00655G, Communication
Yini Liang, Aiqun Gu, Shanling Wang, Yi He, Shuping Zheng, Jian Guo, Filippo S. Boi
The recent discovery of an innovative chemical vapour synthesis (CVS) approach for the encapsulation and stabilization of high-spin ferromagnetic γ-Fe nanocrystals inside carbon nano-onions (CNOs) has attracted significant attention.
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Heteroepitaxial growth modes revisited

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00664F, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jonas Johansson
It is well known that the outcome of a thin film deposition experiment on a foreign substrate is determined by the surface end interface energetics, which can be collected in...
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Understanding the structural landscape of Mn-based MOFs formed with hinged pyrazole carboxylate linkers

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00881A, Paper
Josephine Frances Smernik, Pol Gimeno-Fonquernie, Jorge Albalad, Tyla Shanai Jones, Rosemary Young, Neil R. Champness, Christian J Doonan, Jack D. Evans, Christopher J Sumby
Metal-organic frameworks (MOFs) capable of post-synthetic metalation (PSMet) have garnered significant interest as supports for catalytic metals. The Mn-based MOF, MnMOF-1 (([Mn3(L2Me)3] where L2Me = bis-(4-carboxyphenyl-3,5-dimethylpyrazolyl)methane), has been an exemplar...
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Emerging porous solids and sonochemistry

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00826F, Highlight
Seyoung Koo, Dong Won Kang
This review provides a comprehensive overview of emerging porous materials and their sonochemical applications.
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Investigation of the preparation, characterization, and whitening activity of glabridin and oxymatrine co-amorphous

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00807J, Paper
Peiyi Liang, Yi Hu, Zhuxian Wang, Yinglin Guo, Hongkai Chen, Cuiping Jiang, Quanfu Zeng, Chunyan Shen, Yufan Wu, Li Liu, Yankui Yi, Hongxia Zhu, Zhijun Yang, Qiang Liu
Glabridin (Gla) is a natural active ingredient extracted from licorice root with good whitening activity. However, its poor solubility limits its further application. Therefore, this study aimed to develop a...
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Constructing a pyrene-based dimer in a crystal by adjusting the steric hindrance over the pyrene plane

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00744H, Paper
Zhou-An Xia, Xiangyu Zhang, Chang Xi, Qing Bai, Haichao Liu, Shi-Tong Zhang, Bing Yang
The presence of an ortho-linked substituent in pyrene can lead to steric hindrance on one side of the pyrene plane, which prevents the formation of undesired interactions and promotes the selective formation of dimers in a desired orientation.
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