Cation exchange in an anionic Metal-organic Framework enhancing propylene/propane separation

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00761H, Paper
Xue Zhang, Huijuan Tang, Min Zeng, Rong Yang, Yu Wang, Kaijie Chen
Highly selective adsorptive separation of propylene/propane (C3H6/C3H8) using metal-organic frameworks (MOFs) is a promising approach to reducing energy consumption in the chemical industry. Here we report a 3D anionic MOF...
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Melting pseudosymmetry and thermal expansion in 3-benzoylpropionic acid

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00940H, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tomasz Poręba, Marcin Świątkowski, Giorgia Confalonieri
3-Benzoylpropionic acid undergoes continuous transition associated with pseudosymmetry melting upon heating. The transition stems from a directional steric crowding, which refutes the recent premise of its colossal thermal expansion.
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NaCo7.38(PO4)4Cl4 in a series of homeotype compounds with stable cationic substructures derived from the sulphohalite archetype

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00819C, Paper
Olga Vsevolodovna Yakubovich, Galina Kiriukhina, Sergey Vladimirovich Simonov, Anatoly Volkov, Olga Dimitrova
In this paper, we present the synthesis and characterization of a Cl-bearing member of the phosphate family of compounds with a tetragonal crystal structure and similar topology in the basic...
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Crystallisation of organic hydrates by sublimation

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00732D, Paper
Open Access Open Access
Alexandra L. Volkwyn, Delia A. Haynes
Hydrates of organic molecules can be crystallised by sublimation if there is a strong hydrogen bond to water in the solid hydrate.
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Understanding of the difference in packing density of some energetic isomers

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00876B, Paper
Rong Wang, Yaoyao Linghu, Kai Zhong, Chaoyang Zhang
This work describes the underlying mechanism for the packing density differences in energetic isomers and presents a strategy for constructing high density energetic compounds.
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Kinetics or thermodynamics? Extolling their role to modulate the crystal phases and luminescence of KY3F10:Eu3+ powders

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00614J, Paper
Open Access Open Access
Pablo Serna-Gallén, Héctor Beltrán-Mir, Eloísa Cordoncillo
This study demonstrates the interplay between thermodynamics and kinetics in the transition-phase pathway and the isolation of specific KY3F10 polymorphs.
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Dichlorosubstitution as a steering tool in hydrogen bonded cocrystals: the nature of rigid and flexible coformers in crystal structures

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00672G, Paper
Ritesh Dubey, Sandeep Singh
Dichlorosubstitution is utilized as a chemical probe to explore the landscape of phenol-pyridine based cocrystals.
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Synthesis, characterization and properties of new heat resistant energetic materials based on two C–C bridged pyrazole and benzene skeletons

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00530E, Paper
Rongzheng Zhang, Yuangang Xu, Feng Yang, Pengcheng Wang, Qiuhan Lin, Hui Huang, Ming Lu
C–C bridged pyrazole and benzene skeletons were used to design explosives 1c and 2c with high thermal stabilities, respectively.
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Progresses on the regulation of pathological crystallization

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00192J, Highlight
Zhonghua Li, Yingshuang Meng, Mingyang Yu, Xiaobin Jiang, Gaohong He
When the biological environment deviates from a narrow range of internal balance, some substances are crystallized in body fluids and adhere to the surface of human tissues. It causes inflammation,...
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Assembling silver(I) coordination polymers of an NS4-macrocycle via an endo/exocyclic coordination mode

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00886J, Paper
Seulgi Kim, Joon Rae Kim, Shim Sung Lee, Eunji Lee
Networking of molecular hosts via non-covalent interactions has become one of the central topics in crystal engineering. We herein report the self-assembly of silver(I) coordination polymers with an NS4-macrocycle (L)...
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