Self-assembly of a metal–organic cage-like structure bearing cofacial redox-active bis-(o-semiquinone) copper(II) units

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02855K, Paper
Anna V. Cherkasova, Anton V. Cherkasov, Konstantin A. Martyanov, Artem S. Bogomyakov, Victor N. Khrustalev, Alexander A. Kissel, Konstantin A. Kozhanov, Viacheslav A. Kuropatov, Vladimir K. Cherkasov
We report the efficient formation of dinuclear redox-active metallacycles with a metal–organic cage-like structure during the interaction of ditopic dioxolene ligands with copper.
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Differential fluorescent response to amino acids based on metal–organic framework Zn-PBC

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02522E, Paper
Wenxin Lin, Yijia Wang, Haoke Zhang, Kei Hoi Shan, Panpan Si, Shijiang Yu, Zhen Wang, Dian Zhao, Junkuo Gao, Minghua Wu, Ben Zhong Tang
Zn-PBC, a metal-organic framework with ideal fluorescent property was prepared. It exhibited differential fluorescent response to different kinds of amino acids, which might provide a strategy to design MOF-based sensors for biomolecules in future.
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Hydrogen peroxide photo-fuel cells

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02518G, Frontier
Hiroaki Tada
H2O2-photofuel cell (PFC) is an important photoelectrochemical device contributing to the realization of a solar-driven clean energy cycle named the “hydrogen peroxide-keyed energy cycle” through combination with the photocatalytic H2O2 synthesis.
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Recent advances in the nanoarchitectonics of metal–organic frameworks for light-activated tumor therapy

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02725B, Perspective
Huijuan Duan, Fang Wang, Weizhe Xu, Gang Sheng, Zhaogang Sun, Hongqian Chu
The application of nMOFs to antitumor therapy, including drug delivery strategies, photodynamic therapy (PDT), photothermal therapy (PTT), and combination therapy, is presented.
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MnOxHy-modified CoMoP/NF nanosheet arrays as hydrogen evolution reaction and oxygen evolution reaction bifunctional catalysts under alkaline conditions

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02467A, Paper
Xuemin Wang, Ke Zhang, Yuhan Xie, Dehua Yu, Haoze Tian, Yongbing Lou
The nanosheet arrays of MnOxHy/CoMoP/NF exhibited exceptional hydrogen evolution reaction and oxygen evolution reaction activities.
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Metal coordination to solute binding proteins – exciting chemistry with potential biological meaning

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02417B, Paper
Kinga Garstka, Denise Bellotti, Joanna Wątły, Henryk Kozłowski, Maurizio Remelli, Magdalena Rowińska-Żyrek
ZnuA and AztC, solute binding proteins from Paracoccus denitrificans, bind Zn(II) and Ni(II) via their outercellular His-rich loop regions.
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Effects of oxygen functionalities on hydrous hydrazine decomposition over carbonaceous materials

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02310A, Paper
Open Access Open Access
Silvio Bellomi, Ilaria Barlocco, Simone Tumiati, Patrizia Fumagalli, Nikolaos Dimitratos, Alberto Roldan, Alberto Villa
The structure-activity relationship of oxygen functionalities on carbon materials for the hydrazine decomposition reaction was elucidated by combining experiments and modelling, revealing carbon-oxygen double groups as active sites.
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Four- and three-coordinate planar iron(II) complexes supported by bulky organosilyl ligands

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02219F, Paper
Reon Ishii, Minesato Nakagawa, Yoshimasa Wada, Yusuke Sunada
Four- and three-coordinate iron(II) bis(silyl) complexes were prepared and their catalytic performance in hydrosilylation reactions was investigated.
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Synthesis and feasibility studies of doping U at Ti site of Y2Ti2O7 as a radioactive waste immobilization matrix

Dalton Trans., 2023, 52,14170-14181
DOI: 10.1039/D3DT02727A, Paper
Nitin Gumber, Muhammed Shafeeq, Santosh K. Gupta, Rohan Phatak, Uttam Kumar Goutam, Ravi Kumar, Rajesh V. Pai
The article summarieses the crystal chemistry of Y2Ti2O7 for the Incorporation of U at Ti site as nuclear waste host matrix for nuclear industry.
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Fabrication of bimetallic-doped materials derived from a Cu-based complex for enhanced dye adsorption and iodine capture

Dalton Trans., 2023, 52,14220-14234
DOI: 10.1039/D3DT02749J, Paper
Ai-Ai Yang, Jian-Peng Cui, Yu Liu, Xiao-Sa Zhang, Ze-Bang Sun, Nan Luo, Wen-Ze Li, Jian Luan
A novel 1D binuclear Cu-based complex had been designed and used to synthesize carbon-based metal/non-metal-doped materials by a facile method. The iodine sorption/release and dyes adsorption capabilities have been investigated in detail.
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