Role of ancillary ligands in selectivity towards acceptorless dehydrogenation versus dehydrogenative coupling of alcohols and amines catalyzed by cationic ruthenium(II)–CNC pincer complexes

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT03149G, Paper
Rahul Kumar Singh, Dibya Yadav, Shilpi Misra, Amrendra K. Singh
The unexpected reversal in the catalytic activity of cationic Ru(II)–CNC pincer complexes for dehydrogenative coupling compared to acceptorless dehydrogenation can be explained using the trans effect of the auxiliary ligands (CO > COD > DMSO ≈ PPh3).
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Hydrogenation and dehydrogenation of N-heterocycles under Cp*Co(III)-catalysis

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT03161F, Communication
Pardeep Dahiya, Nidhi Garg, Rinaldo Poli, Basker Sundararaju
One-step bidirectional hydrogenation–dehydrogenation of N-heterocycles is demonstrated under Cp*Co(III)-catalysis in water using HCO2H as an LOHC or O2 as an oxidant.
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Correction: Silver complexes with substituted terpyridines as promising anticancer metallodrugs and their crystal structure, photoluminescence, and DNA interactions

Dalton Trans., 2023, 52,14242-14242
DOI: 10.1039/D3DT90168H, Correction
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiahe Li, Zhiyuan Wang, Zhongting Chen, Xingyong Xue, Kejuan Lin, Hailan Chen, Lixia Pan, Yulin Yuan, Zhen Ma
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Slow magnetic relaxation in 8-coordinate Mn(II) compounds

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02307A, Paper
Li-Xin Wang, Xiao-Fan Wu, Xin-Xin Jin, Jia-Yi Li, Bing-Wu Wang, Ji-Yan Liu, Jing Xiang, Song Gao
Four mononuclear 8-coordinate Mn(II) compounds have been obtained and all the compounds show field-induced slow magnetic relaxation (SMR) behaviors.
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Tuning the morphology to enhance the catalytic activity of α-Ag2WO4 through V-doping

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02352D, Paper
Open Access Open Access
Katiana Lima Patrocinio, Jeziel Rodrigues Santos, Luis Ignacio Granone, Miguel Adolfo Ponce, Maria Sandra Churio, Lara Kelly Ribeiro, Marcio Daldin Teodoro, Rosa Llusar, Juan Andrés, Elson Longo, Marcelo Assis
Here, we present the synthesis of a highly efficient V-doped α-Ag2WO4 catalyst for the oxidation of sulfides to sulfones, exhibiting a high degree of tolerance towards various sensitive functional groups.
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Microstructure optimization strategy of ZnIn2S4/rGO composites toward enhanced and tunable electromagnetic wave absorption properties

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02338A, Paper
Ran Xu, Man He, Shuangjiang Feng, Yanmei Liu, Chunfeng Mao, Yongjuan Wang, Xiaohai Bu, Meiyun Zhang, Yuming Zhou
ZnIn2S4/rGO-1 and ZnIn2S4/rGO-2 composites with flower-like and cloud-like morphologies were fabricated via a convenient hydrothermal method, displaying excellent microwave attenuation performance and tunable absorption bands.
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Synthesis, structure and characterizations of Cd2TeO3Cl2 with unprecedented [Cd2O6Cl4] octahedral dimers

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02515B, Paper
Linan Wang, Chen Bai, Yingying Kong, Maqsood Iqbal, Yu Chu, Junjie Li
A new mixed anionic compound Cd2TeO3Cl2 with unprecedented [Cd2O6Cl4] octahedral dimers has been synthesized, and millimeter-scale single crystals of Cd2TeO3Cl2 have been grown by vertical Bridgman method with CdCl2 as...
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Topochemical Reaction Induced the Formation of Bi2S3 Micro-straws from Bi-MOF for Ultra-long Zn Storage Life

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02448B, Paper
Lei Gou, Kai Liang, Wen-Yan Wang, YaTing Lei, Shoulin Xie, Dingkai Wei, Dong-Lin Li, Xiaoyong Fan
Aqueous zinc ion batteries (ZIBs) are considered as a promising energy storage in the post-lithium-ion era, due to their high energy density, low cost, high safety, and environmental benignity, however...
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Synthesis and bonding analysis of pentagonal bipyramidal rhenium carboxamide oxo complexes

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02617E, Paper
Noah D. McMillion, Quinton J. Bruch, Chun-Hsing Chen, Faraj Hasanayn, Alexander J. M. Miller
Proton-switchable access to seven-coordinate ONNO dicarboxamide and NNNN dicarboxamidate rhenium oxo complexes provides a platform for understanding thermodynamics and bonding in pentagonal bipyramidal complexes.
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Correction: Synthesis and characterization of heterometallic rings templated through alkylammonium or imidazolium cations

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT90159A, Correction
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rajeh Alotaibi, Amy Booth, Edmund Little, Adam Brookfield, Amritroop Achari, Selena J. Lockyer, Grigore A. Timco, George F. S. Whitehead, Iñigo J. Vitórica-Yrezábal, Nicholas F. Chilton, Rahul R. Nair, David Collison, Richard E. P. Winpenny
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