Decoding the Puzzle: Recent Breakthroughs in Understanding Degradation Mechanisms of Li-ion Batteries

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02957C, Perspective
Aditya Narayan Singh, Md. Kamrul Hasan, Chinna Bathula, Kyung-Wan Nam
Lithium-ion batteries (LIBs) remain at the forefront of energy research due to their capability to deliver high-energy-density. Understanding their degradation mechanism has been essential due to their rapid engagement in...
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Evaluation of tin nitride (Sn3N4) via atomic layer deposition using novel volatile Sn precursors

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02138F, Paper
Hyeonbin Park, Heenang Choi, Sunyoung Shin, Bo Keun Park, Kibum Kang, Ji Yeon Ryu, Taeyong Eom, Taek-Mo Chung
Novel tin precursor with iminopyrrolidine moieties was synthesized and investigated for Sn3N4 thin films via the ALD process.
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Ultralow Ruthenium Modification of Cobalt Metal–Organic Frameworks for Enhanced Efficient Bifunctional Water Splitting

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02712K, Paper
Yuanyuan Wu, Xuejiao Gu, Wei Jiang, Jihui Lang, Yunchao Ma, Yang Lu, Xiaotian Yang, Chunbo Liu, Guangbo Che
Hydrogen economy has emerged as a promising alternative to the current hydrocarbon economy. It involves harvesting renewable energy to split water into hydrogen and oxygen and then further utilising clean...
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Azaacene Containing Iridium(III) Phosphors: Elaboration of π-Conjugation Effect and Application in Highly Efficient Solution-Processed Near-infrared OLEDs

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02629A, Paper
Min Li, Li Wang, Caifa You, Denghui Liu, Kai Zhang, Weiguo Zhu
Azaacenes have attracted wide research interest due to their tremendous potential in organic electronics. However, near-infrared (NIR) light-emitting iridium(III) phosphors bearing azaacene derivatives are rarely investigated. In this contribution, two...
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CoS2@C catalyzes polysulfide conversion to promote rate and cycling performances of lithium—sulfur batteries

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02769D, Paper
Yufei Zhang, Xinhang Liu, Qi Jin, Fengfeng Han, Zhiguo Zhang, Xitian Zhang, Lili Wu
Lithium-sulfur (Li-S) batteries have been considered as one of the most promising candidates for next-generation energy storage devices due to their high theoretical energy density and low cost. Nonetheless, the...
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Color-tunable luminescence based on the efficient energy transfer of a Tm–Dy system for optical thermometry and white LED lighting

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02770H, Paper
Qi Xiao, Xingyu Wu, Na Zhou, Zhi Li, Yuqi Liu, Xinyao Dong, Xiumei Yin, Xixian Luo
Dy3+,Tm3+ co-doped K3Y(PO4)2 phosphors with high efficiency energy transfer can achieve color-tunable luminescence and have potential application prospects in the fields of optical temperature measurement and white LED lighting.
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An ethynyl-modified interpenetrated metal–organic framework for highly efficient selective gas adsorption

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02834H, Paper
Xueyue Yu, Ziyang Huang, Rajamani Krishna, Xiaolong Luo, Yunling Liu
Compound 1 has been constructed by using expanded ethynyl-modified tetracarboxylates ligands and Cu2(CO2)4 paddle-wheel building units, and exhibits excellent adsorption and separation behavior for light hydrocarbons.
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Carbon-supported T-Nb2O5 nanospheres and MoS2 composites with a mosaic structure for insertion–conversion anode materials

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02224B, Paper
Shaohao Li, Caifeng Pan, Zhaohui Zhao, Wei Yang, Hanbo Zou, Shengzhou Chen
In this paper, we load carbon into MoS2 with T-Nb2O5 nanospheres using hydrothermal synthesis, add polydopamine carbon and heat treat. This accelerates charge transfer and reduces volume expansion for excellent T-Nb2O5@MoS2@C electrode performance.
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C–H, Si–H and C–F abstraction with an extremely electron poor I(III) reagent

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT03266C, Paper
Tania, Marcus Sceney, Jason D. Bennetts, Lachlan Barwise, Keith F. White, Jason L. Dutton
The recently discovered I(III) reagent NO2-C6H4-I(OTf)2 is found to rapidly react with hydride sources, including HSiEt3 and relatively hydridic C–H precursors.
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Synthesis of Nitrogen Mustards on Cobalt(III)

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT01634J, Paper
Rasika Janadari Kariyawasam, Ramin Zibaseresht, Matthew Ian James Polson, Joanna C.C. Houlihan, Jan L. Wikaira, Richard M Hartshorn
Bis(bidentate) and bis(tridentate) Co(III) complexes of N-(2-hydroxyethyl)ethane-1,2-diamine (heen), 2-[(2-aminoethyl)amino]ethan-1-olate (heen-H), or N-(2-chloroethyl)ethane-1,2-diamine (ceen) ligands have been synthesised, and a range of reaction conditions established for their syntheses by different routes....
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