Binuclear cobalt(II) and two-dimensional manganese(II) coordination compounds self-assembled by mixed bipyridine-tetracarboxylic ligands with single-ion magnet properties

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT03016D, Paper
Dongqing Wu, Kusum Kumari, Yi Wan, Xueling Gao, Mengxi Guo, Genyan Liu, Dong Shao, Bin Zhai, Saurabh Kumar Singh
A cobalt(II) complex and manganese(II) coordination polymer, formulated as [Co2(H2btca)(mbpy)4][H2btca]·4H2O (1) and {Mn2(btca)(mbpy)2(H2O)2}n (2) (H4btca = 1,2,4,5-Benzenetetracarboxylic acid; mbpy = 4,4'-Dimethyl-2,2'-bipyridyl), constructed by mixed bipyridine-tetracarboxylic ligands were synthesized and characterized....
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Naphthoyl Benzhydrazine – Decorated Binuclear Arene Ru(II) Complexes as Anticancer Agents Targeting Human Breast Cancer Cells

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02552G, Paper
Abirami Arunachalam, Devan Umapathy, Ramesh Rengan, Antony Joeph Velanganni Arockiam, Jan Grzegorz Małecki
Breast cancer is the most dangerous cancer in women and its fatality rate has increased over the decade ahead. To develop more potent and target-specific breast cancer drugs, six arene...
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Electron density effect of aromatic carboxylic acids in naphthalenediimide-based coordination polymers: from thermal electron transfer and charge transfer to photoinduced electron transfer

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT03069E, Paper
Gao-Peng Li, Jing Zhang, Wan-Wan Ren, Si-Nan Wang, Ying-Xia Wang, Yunlong Fu, Yao-Yu Wang
Various naphthalenediimides (NDIs) based electron donor-acceptor coordination polymers (D-A CPs) have been constructed and used to explore charge transfer (CT) and electron transfer (ET) behaviors. Up to now, significant progress...
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Synthesis of Fluorinated Aminium Cations Coupled with Carborane Anions For Use as Strong One-Electron Oxidant

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02127K, Paper
Jillian J. Davidson, S. Olivia Gunther, Derek W. Leong, Oleg V. Ozerov
Synthesis of a series of hydrocarbon-soluble triarylamines bearing F, CF3, and Br substituents showing quasi-reversible redox events in the 0.59 – 1.32 V range is reported. Chemical oxidation of the...
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Multivariate Metal-organic Frameworks Generated through Post-synthetic Modification: Impact and Future Directions

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT01936E, Frontier
Kyle Smith, Kyriakos Stylianou
Reticular chemistry has proven to be invaluable over time, thanks to the structural versatility, and tailored porosity observed in structures like metal-organic frameworks (MOFs), covalent-organic frameworks (COFs), and metal-organic polyhedra...
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A simple MOF constructed by Pb(II) with strong polarizing force: a filler of Nafion membrane to increase proton conductivity

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02911E, Paper
Jiawei Liu, Li Ding, Huiqi Zou, zhipeng Huan, Hou-Ting Liu, Jing Lu, Suna Wang, Yun-Wu Li
Metal-organic frameworks (MOFs) are one kind of promising competitive candidates as fillers of Nafion proton exchange membrane (PEM). More and more efforts have been made to explore the method of...
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Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02472E, Communication
Mehdi Moussa, Eva-Maria Rummel, Maria Eckhardt, Christoph Riesinger, Manfred Scheer
The reaction of RC≡P (R = Me, tBu, iPr) with Co2(CO)8 and Fe2(CO)9 under mild conditions led to unpredictable fragmentations of the C-P triple bond and subsequent formation of clusters...
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Enhanced catalysis of vanadium-substituted Keggin-type polyoxomolybdate supported on M3O4/C (M=Fe or Co) surface enables efficient and recyclable HMF oxidation to DFF

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02935B, Paper
Yun-Dong Cao, Wen-Xia Mu, Mengdi Gong, Lin-Lin Fan, Jie Han, Hong Liu, Bin Qi, Guanggang Gao
In the reaction of oxidizing 5-hydroxymethylfurfural (HMF), attaining high efficiency and selectivity in the conversion of HMF to DFF presents a challenge due to the possibility of multiple products. Polyoxometalates...
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Synthesis, X-ray Characterization and DFT analysis of Dicyanidoaurate Telluronium salts: on the importance of charge assisted chalcogen bonds

Dalton Trans., 2023, Accepted Manuscript
DOI: 10.1039/D3DT02787B, Paper
Open Access Open Access
Simone Ghinato, Alessia Giordana, Eliano Diana, Rosa Maria Gomila, Emanuele Priola, Antonio Frontera
In this manuscript we report the synthesis and X-ray characterization of two cyanidoaurate telluronium salts, namely (3-fluorophenyl)(methyl)(phenyl)telluronium dicyanidoaurate [(3-F-Ph)(Me)(Ph)Te][Au(CN)2] (1) and methyldiphenyltelluronium dicyanidoaurate [(Me)(Ph)2Te][Au(CN)2] (2). In the solid state, the...
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Structure–activity effects in the anti-leishmanial activity of di-alkyl gallium quinolin-8-olates

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02542J, Paper
Rebekah N. Duffin, Philip C. Andrews
The anti-Leishmanial activity and cytotoxicity of novel alkyl gallium quinoline-8-olates [Ga(R)2quin] (R = Et, nBu, sBu, tBu, iPr, hex) have been assessed, with the nBu complex found to exhibit a high degree of activity and selectivity.
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