Faraday Discuss., 2023, 245,380-390
DOI: 10.1039/D2FD00180B, Paper

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Alexander K. Lemmens, Cameron J. Mackie, Alessandra Candian, Timothy M. J. Lee, Alexander G. G. M. Tielens, Anouk M. Rijs, Wybren Jan Buma
Calculated infrared absorption intensities of PAHs that underlie the interpretation of infrared emission from the ISM are validated with experiments. An adjusted emission model implies that typical PAH sizes are smaller than previously estimated.
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Faraday Discuss., 2023, 245,11-51
DOI: 10.1039/D3FD00106G, Paper

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Cecilia Ceccarelli
This Spiers Memorial Lecture introduces the Faraday Discussion on ‘Astrochemistry at high resolution’, focusing on the special case of interstellar complex organic molecules (iCOMs).
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Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00079F, Paper

Kiwoong Lee, Jeff Sakamoto
This study demonstrates that the stability of cycling in situ Li anodes depends on their depth of discharge (DOD). High DOD cycling results in unstable performance due to the accumulation of interfacial degradation at Li/LLZO interfaces.
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Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00096F, Paper

Pierre L. Stigliano, Nagore Ortiz-Vitoriano, Lidia Medinilla, Jason E. Bara, Juan Miguel López del Amo, Luis Lezama, Maria Forsyth, David Mecerreyes, Cristina Pozo-Gonzalo
A green, low-toxic diglyme isomer, 1,2,3-trimethoxypropane, has been studied, for the first time, as the electrolyte in sodium–air batteries reaching 2.31 mA h cm⁻² discharge capacity and with NaO₂ as the main discharge product.
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Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00088E, Paper

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Soumyadip Mondal, Rajesh B. Jethwa, Bhargavi Pant, Robert Hauschild, Stefan A. Freunberger
We have shown direct spectroscopic evidence of the previously identified pathways for singlet oxygen (¹O₂) formation in non-aqueous oxygen redox chemistry.
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Faraday Discuss., 2023, 245,52-79
DOI: 10.1039/D3FD00010A, Paper

Ewine F. van Dishoeck, S. Grant, B. Tabone, M. van Gelder, L. Francis, L. Tychoniec, G. Bettoni, A. M. Arabhavi, D. Gasman, P. Nazari, M. Vlasblom, P. Kavanagh, V. Christiaens, P. Klaassen, H. Beuther, Th. Henning, I. Kamp
Early results from JWST-MIRI programs on low- and high-mass protostars and disks show significant diversity in their mid-infrared spectra, most notably for CO₂, H₂O and C₂H₂. Benzene is detected in disks around very low mass stars.
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Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00081H, Paper

Daniel Córdoba, Leandro N. Benavides, Daniel H. Murgida, Hernan B. Rodríguez, Ernesto J. Calvo
We have operando detected the formation of singlet oxygen in a real Li–O₂ battery by DMA fluorescence decay and its suppression by using physical quenchers, reaching an extended battery cycle life due to mitigation of spurious reactions
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Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00071K, Paper

Jinwen Liu, Limin Guo, Ye Xu, Jun Huang, Zhangquan Peng
This work identifies the key products and intermediates (O₂⁻, KO₂ and K₂O₂) and reveals their dependency on the electrode potential by combining in situ Raman spectroelectrochemistry and density functional theory calculations.
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Faraday Discuss., 2023, 245,327-351
DOI: 10.1039/D3FD00057E, Paper

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Nadia Balucani, Adriana Caracciolo, Gianmarco Vanuzzo, Dimitrios Skouteris, Marzio Rosi, Leonardo Pacifici, Piergiorgio Casavecchia, Kevin M. Hickson, Jean-Christophe Loison, Michel Dobrijevic
Low temperature kinetics, crossed beam experiments, calculations of the underlying potential energy surface and of the product branching fractions for the N(²D) + benzene reaction are reported. The results have been used in a photochemical model of Titan.
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Faraday Discuss., 2023, 245,586-608
DOI: 10.1039/D3FD00039G, Paper

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Marie Van de Sande, Catherine Walsh, Tom J. Millar
The first AGB chemical kinetics model that includes porosity, dust–gas chemistry and companion UV photons, allows us to unravel the interplay of the complexities and identify suites of molecules to determine the presence of a companion star.
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