Triggering synergistic electronic promoting effect through oxygen doping to promote electrochemical nitrogen reduction on metal-free electrocatalyst

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01673K, Research Article
Na Xu, Qiyang Cheng, Mengfan Wang, Yanzheng He, Haoqing Ji, Federico Rosei
Electrocatalytic nitrogen reduction reaction (NRR) as an alternative approach to the energy-intensive Haber-Bosch process for artificial ammonia synthesis has attracted extensive attention. Previous reports have suggested that metal-free electrocatalyst, such...
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Th@C2(8)-C84 and Th@Cs(15)-C84: impact of actinide metal ions on the electronic structure of actinide endohedral metallofullerenes

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01215H, Research Article
Ning Chen, Yang-Rong Yao, Tiantian Cao, Qingyu Meng, Ze Fu, Yi Shen, Qin Wang, Yingjing Yan, Bing Zhao, Wenxia Wang, Khaoula Merimi, Antonio Rodriguez-Fortea
Two novel thorium-based endohedral metallofullerenes (EMFs), Th@C2(8)-C84 and Th@Cs(15)-C84, have been successfully synthesized and fully characterized by MALDI-TOF mass spectrum, single-crystal X-ray diffraction, UV-vis-NIR spectroscopy, and cyclic voltammetry. The molecular...
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Abiotic Transformations of Nitrogen mediated by Iron Sulfides and related species from Early Earth to Catalyst Design

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01553J, Review Article
C. Felipe Garibello, Daniel S Eldridge, Francois Malherbe, Rosalie K Hocking
Nitrogen fixation and the cycles of nitrogen on Earth are key to life as we know it and are critical to both life and modern agriculture. Despite its importance, there...
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An eco-friendly electrolyte additive for high-power primary aqueous Mg-air batteries

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01223A, Research Article
Bingjie Ma, Wenbin Jiang, Liuzhang Ouyang, Hai-Wen Li
The performance of aqueous Mg-air batteries is predominantly limited by two factors: the high polarization effect caused by the adherence of surface passive film, and the low efficiency resulting from...
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Achieving Broadband Ultraviolet to Mid-Infrared Transparency in Germanate-based Nonlinear Optical Crystals Cs3REGe3O9 (RE = Y, Gd)

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01807E, Research Article
Jinmiao Jiao, Conggang Li, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu
Nonlinear optical (NLO) materials currently attract significant interest and hold paramount importance in the optoelectronic field. Nevertheless, the fabrication of NLO crystals capable of transmitting ultraviolet to mid-infrared wavelengths remains...
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Unlocking the catalytic potential of nickel sulfide for sugar electrolysis: green hydrogen generation from kitchen feedstock

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01686B, Research Article
Supriya A. Patil, Atul C. Khot, Kalyani D. Kadam, Hoa Thi Bui, Hyunsik Im, Nabeen K. Shrestha
The first-ever demonstration of Ni7S6/NF-based electrolyzer with sugar or orange-juice as active electrolyte for an alternative anodic oxidation reaction in water-electrolysis and achieving a higher rate of green-hydrogen at a lower cell voltage.
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Sheet-Like Silicalite-1 Single Crystals with Embedded Macropores Displaying Superior Catalytic Performance

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01712E, Research Article
Yanfei Zhang, Liang Qi, Xiaomin Zhang, Qike Jiang, Peng Lu, Lei Xu, Alexis T. Bell
Unique sheet-like Silicalite-1 single crystals containing intracrystalline macropores (HMS-Silicalite-1) were prepared by urea-assisted, dry-gel synthesis, which uses mesoporous silica spheres (MSS) as both the silica precursor and the macropore template....
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Luminescence Detection of CH2Cl2 via Varying Cu∙∙∙Cu Interaction in a Flexible Porous Coordination Polymer

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01723K, Research Article
Wei-Jie Zhang, Wan-Tao Chen, Chen-Hui Li, Wen-Zhu Sun, Jia-Wen Ye, Ling Chen, Hai-Ping Wang, Xiao-Ming Chen
Due to the weakness of interaction between chlorohydrocarbon and host framework, the development of reversible and vapochromic coordination polymer (CP)-based luminescence sensors to CH2Cl2 with fast response is still challenging....
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Advances in research on the inhibitory effect of 3D current collector structures for lithium dendrites

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01290E, Review Article
Song-Bai Xiang, Yu Fu, Cheng-Ri Yin, Yue Hou, Hailing Tian, Zhenxing Yin
Lithium is considered the "Holy Grail" of anode materials in lithium metal batteries, due to its extremely low electrochemical potential and high specific capacity. However, during the charging/discharging process, the...
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Supercritical relaxor phase boundary for ultrahigh electrostrictive properties

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01636F, Research Article
Qinghu Guo, Dong-Xu Li, Zhonghua Yao, Huajun Sun, Hua Hao, Hanxing Liu, Shujun Zhang
Electrostrictive materials have been actively studied for the applications in precision machinery, laser communication, and biological microscopy due to their numerous advantages, including high resolution, negligible hysteresis, low heat dissipation,...
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