Dry approach production of a garnet solid electrolyte membrane for lithium batteries

Inorg. Chem. Front., 2023, 10,6023-6031
DOI: 10.1039/D3QI01319G, Research Article
Qiulin Li, Yiqiu Li, Hao Chen, Hui Liu, Lianjie Li, Jie Song, Maowen Xu, Shu-Juan Bao
Ultrathin garnet solid electrolyte membranes were successfully prepared by dry electrode technology, in addition to investigating the mechanism of membrane formation and electrochemical properties.
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Group 14 metallole dianions as η5-coordinating ligands

Inorg. Chem. Front., 2023, 10,5509-5516
DOI: 10.1039/D3QI01342A, Chemistry Frontiers
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaofei Sun, Peter W. Roesky
The coordination chemistry of group 14 metallole dianions, compared to monoanionic cyclopentadienides, is underexplored. This perspective reviews η5-coordination in group 14 metallole dianions, revealing their potential in organometallic chemistry.
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Synthesis of chiral high-entropy sulfides for non-linear optical applications

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01214J, Research Article
Open Access Open Access
Nethmi W. Hewage, Gayatri Viswanathan, Philip Yox, Kui Wu, Kirill Kovnir, Georgiy Akopov
Non-centrosymmetric semiconductors may exhibit non-linear optical (NLO) properties.
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A 3D lead chloride hybrid exhibits self-trapped emission and exceptional stability

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01350B, Research Article
Mohamed Saber Lassoued, Qian-Cheng Luo, Yan-Zhen Zheng
A new 3D lead chloride hybrid, (H2MPP)2Pb5Cl14, has been isolated. (H2MPP)2Pb5Cl14 exhibits broadband emission with a large Stokes shift and a high color rendering index (CRI), which is mainly attributed to the self-trapped exciton mechanism (STE).
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Investigating the role of oxygen vacancies in metal oxide for enhanced electrochemical reduction of NO3− to NH3: mechanistic insights

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01536J, Review Article
Sadeeq Ullah, Shiyong Wang, Muhammad Sohail Ahmad, Hafiz M. Adeel Sharif, Qingling Liu, Tetsuya Kida, Aamir Shafique, Majeed Ur Rehman, Gang Wang, Jieshan Qiu
Ammonia (NH3) is a crucial chemical commodity used extensively in fertilizer production and as a renewable potential energy carrier.
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Prussian blue-derived multiple yolk–single shell-structured Se-doped Fe7S8@NC@C microcube composites as high-rate anodes for sodium-ion batteries

Inorg. Chem. Front., 2023, 10,6105-6115
DOI: 10.1039/D3QI01397A, Research Article
Qingping Li, Peng Wang, Yuxiang Chen, Xiangyue Liao, Ransha Deng, Qiaoji Zheng, Dunmin Lin
The yolk-shell structured provides sufficient void space; the dual-carbon layer acts as a rigid skeleton. Meanwhile, Se-doping improving the electrical conductivity and enlarging the interlayer distance to enhance Na storage.
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Subtly regulating layered tin chalcogenide frameworks for optimized photo-induced carrier separation

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01439H, Research Article
Chaozhuang Xue, Rui Li, Wenhui Chen, Yingying Zhang, Ningning Zhang, Konggang Qu, Ruiqing Li, Huajun Yang
Elongated distance between adjacent clusters could decrease the photoinduced carrier recombination due to the prolonged intercluster charge transfer process.
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Fabrication of ultrathin two-dimensional MOF nanosheets with cage-like cavities showing excellent adsorption for lead(II)

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01619F, Research Article
Hongwei Sun, Ke-Zhong Wang, Meng-Ru Yao, Cai-Xia Yu, Yue-Hai Song, Jing Ding, Yan-Li Zhou, Dong Liu, Lei-Lei Liu
An ultrathin 2D MOF nanosheet with cage-like cavities was constructed, which showed an outstanding Pb2+ uptake capacity of 738.65 mg g−1 as well as ultrahigh selectivity and anti-interference performance.
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LiVTeO5: a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01715J, Research Article
Yuheng She, Jinmiao Jiao, Zheng Wang, Jing Chai, Song Jie, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li
A novel NLO tellurate crystal, LiVTeO5, was extracted via spontaneous crystallization. It features the attractive merits of a strong SHG response, a large band gap, a wide transmittance range, and a notable birefringence.
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A 3D-printed square-hole electrode for dendrite-free zinc–air batteries

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01506H, Research Article
Chuancheng Mou, Yujia Bai, Yi Zhang, Yijian Liu, Zhen Hu, Jiayu Chen, Genxiang Wang, Xuantao Wu, Hui Wang, Yuhan Sun
A corrosion-resistant electrode was prepared by a combination of 3D printing and etching. It can be stable in alkaline solution for a long time. So the electrode can achieve a cycle life of more than 1000 h.
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