Base-Mediated Carboxylation of C-Nucleophiles with CO2

Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01367G, Review Article
Wenbin Huang, Yanlong Luo
Carbon dioxide (CO2) is an available, abundant, and renewable C1 resource, which could be converted into value-added chemicals. Due to the inherent thermodynamic stability and kinetic inertness, it is difficult...
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Expression of concern: A cascade process for directly converting nitriles (RCN) to cyanamides (RNHCN) via SO2F2-activated Tiemann rearrangement

Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB90149A, Expression of Concern
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Guofu Zhang, Yiyong Zhao, Chengrong Ding
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Improved synthesis of DA364, a NIR fluorescence RGD probe targeting αvβ3 integrin

Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01206A, Paper
Open Access Open Access
Rachele Maschio, Federica Buonsanti, Federico Crivellin, Fulvio Ferretti, Luciano Lattuada, Federico Maisano, Laura Orio, Lorena Pizzuto, Raphael Campanella, Anthony Clouet, Camilla Cavallotti, Giovanni Battista Giovenzana
Optical imaging (OI) is gaining increasing attention in medicine as a non-invasive diagnostic imaging technology and as a useful tool for image-guided surgery. OI exploits the light emitted in the...
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The synthesis of meta-arylphenol derivatives via acid-promoted rearrangement of cyclohexadienones

Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01363D, Paper
Hongyan Xie, Minxiang Zhang, Xueyu Fang, Zhaohua Yan, Hua Yao
A highly effective strategy for the synthesis of meta-arylphenol derivatives through the selective rearrangement of 4-alkyl-4-aryl-2,5-cyclohexadienones under metal-free conditions was developed, in which acid-promoted [1,2]-migration of the aryl group at...
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Improved Lipophilic Probe for Visualizing Lipid Droplets in Erastin-Induced Ferroptosis

Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01545A, Paper
Deeksha Rajput, Paramasivam Mahalingavelar, Virupakshi Soppina, Sriram Kanvah
Studying the viscosity of lipid droplets (LDs) provides insights into various diseases associated with LD viscosity. Ferroptosis is one such process in which LD viscosity increases due to the abnormal...
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Correction: Rhodium(II)-catalyzed transannulation approach to N-fluoroalkylated indoles

Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB90145A, Correction
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Olga Bakhanovich, Blanka Klepetářová, Petr Beier
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Visible-light-driven 1,2-hydro(cyanomethylation) of alkenes with chloroacetonitrile

Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01533E, Communication
Keito Fuke, Tomoya Miura
A regioselective 1,2-hydro(cyanomethylation) of unactivated aliphatic alkenes is reported. A cyanomethyl radical is generated from haloacetonitriles. This radical adds onto alkenes to form alkyl radicals, which undergo the hydrogen atom...
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Photochemically induced chloromethylation/cyclization of benzimidazole derivatives with CCl4/CHCl3

Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01290E, Paper
Yanmin Liu, Ziwei Li, Luyao Yang, Shuo Li, Zhiwei Chen
Herein, it was reported that a series of trichloromethyl/dichloromethyl substituted benzimidazole derivatives were synthesized by dechlorination of CCl4/CHCl3 to form polychloromethyl radicals and cyclization with inactive olefin under purple LED...
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Regio-specific Enzymatic Glucosylation of Triterpenoids from Antrodia camphorata and their Biological Activities

Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01286G, Communication
Huifei Su, Bin Li, Yi Yang, Meng Zhang, Rong Yu, Yang-Oujie Bao, Kuan Chen, Min Ye
The bacterial glycosyltransferase YjiC1 was used to glycosylate triterpenoids from the medicinal fungus Antrodia camphorata. Eleven new compounds were obtained from enzymatic reactions. Glucosylation could increase the inhibitory activities against...
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Palladium-catalyzed decarboxylative α-allylation of thiazolidinones and azlactones with sulfonamido-substituted acyclic allylic carbonates

Org. Biomol. Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3OB01404E, Paper
Han-Wen Rao, Tian-Lan Zhao, Long Wang, Hong-Dan Deng, Yan-Ping Zhang, Yong You, Zhen-Hua Wang, Jian-Qiang Zhao, Wei-Cheng Yuan
A palladium-catalyzed decarboxylative α-allylation of thiazolidinones and azlactones with aza-π-allylpalladium zwitterionic intermediates, in situ generated from sulfonamido-substituted allylic carbonates, is successfully developed. This method allows the formation of a series...
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