Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01312J, Communication

Pradeep Kumar, Deepanshi Saxena, Rahul Maitra, Sidharth Chopra, T. Narender
A simple and efficient protocol has been developed to access thioethers by reacting indoles with p-quinone methides using thiourea as a sulfur source.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01420G, Paper

Open Access

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Hiroyoshi Takamura, Kosuke Hattori, Takumi Ohashi, Taichi Otsu, Isao Kadota
Stereodivergent synthesis of the C61–C74 and C69–C83 fragments of symbiodinolide elucidated the relative configuration of its C61–C83 fragment.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB00931A, Paper

Qiong Liu, Zhaolong Ma, Jing Zhang, Xu-Qin Li
We established a Rh(III) catalyzed C–H carboxymethylation strategy for anilines with vinylene carbonate. This protocol does not require external oxidants. It proceeded smoothly with good functional group tolerance and moderate to good yields.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01361H, Communication

Li Sun, Jiyu Li, Yafei Wu, Ying Li, Junqi Chen, Xiaoye Xia, Chunhao Yuan, Hongchao Guo, Biming Mao
A Pd-catalyzed [4+2] cycloaddition of 2-methylidenetrimethylene carbonate or methylene cyclic carbamate with sulfamate-derived cyclic imines has been successfully developed to afford oxazine or hydropyrimidine derivatives.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01309J, Paper

Aleksandr V. Konovalov, Svetlana G. Churusova, Diana V. Aleksanyan, Ekaterina Yu. Rybalkina, Svetlana A. Aksenova, Alexander S. Peregudov, Zinaida S. Klemenkova, Vladimir A. Kozlov
The facile approaches to α-(aminoalkyl)diphenylphosphine sulfides are devised based on simple transformations of readily available precursors. The compounds obtained are used as building blocks for the production of cytotoxic Pd(II) complexes.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01276J, Review Article

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Aitor Maestro, Mercedes Zurro
A powerful and straightforward way to access a variety of oxa-heterocycles and N-heterocycles: the phosphine-catalysed transformations of o-QM, p-QM and aza-o-QM.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01199B, Paper

Feixue Xue, Chang-Jiang Yang, Tong Tang, Zhengjie He
A one-pot synthesis of 5-(3-oxindolyl)oxazoles has been developed by a sequential annulation/isomerization strategy.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB00860F, Paper

Fen-Dou Wang, Chunmiao Wang, Min Wang, Han Yan, Jin Jiang, Pinhua Li
A new strategy for the preparation of 3-halobenzo[b]thiophenes via a photo-driven halocyclization/demethylation of 2-alkynylthioanisoles with simple alkyl halides was developed.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB00983A, Paper

Mark S. Cooper, Mark C. Norley, Simon Armitage, Joel O. Cresser-Brown, Anthony K. Edmonds, Sean Goggins, Jonathan P. Hopewell, Burhan Karadogan, Kevin A. Knights, Toby J. Nash, Catherine S. Oakes, William J. O'Neill, Simon J. Pridmore, Hannah J. Maple, Graham P. Marsh
Supporting degrader discovery programs in scale and scope: facile access to multi-hundred-gram quantities of the common E3 ligase ligands.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01391J, Paper

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David Almacellas, Célia Fonseca Guerra, Jordi Poater
Cooperative effects cause extra stabilization of hydrogen-bonded supramolecular systems.
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