Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01309J, Paper

Aleksandr V. Konovalov, Svetlana G. Churusova, Diana V. Aleksanyan, Ekaterina Yu. Rybalkina, Svetlana A. Aksenova, Alexander S. Peregudov, Zinaida S. Klemenkova, Vladimir A. Kozlov
The facile approaches to α-(aminoalkyl)diphenylphosphine sulfides are devised based on simple transformations of readily available precursors. The compounds obtained are used as building blocks for the production of cytotoxic Pd(II) complexes.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01424J, Paper

Guanqun Zhan, Fuxin Zhang, Kailing Yang, Tao Yang, Ruixi Zhou, Wenwen Chen, Jingwei Zhang, Xinxin Zhang, Zengjun Guo
Alscholarines A–B, featuring an imidazole ring fused with a 6/5/6/6 tetracyclic skeleton and an unusual 7-oxa-1-azabicyclo[3.2.1]octane moiety with a 6/5/6/6/5 ring system, respectively, were isolated from Alstonia scholaris.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01361H, Communication

Li Sun, Jiyu Li, Yafei Wu, Ying Li, Junqi Chen, Xiaoye Xia, Chunhao Yuan, Hongchao Guo, Biming Mao
A Pd-catalyzed [4+2] cycloaddition of 2-methylidenetrimethylene carbonate or methylene cyclic carbamate with sulfamate-derived cyclic imines has been successfully developed to afford oxazine or hydropyrimidine derivatives.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB00931A, Paper

Qiong Liu, Zhaolong Ma, Jing Zhang, Xu-Qin Li
We established a Rh(III) catalyzed C–H carboxymethylation strategy for anilines with vinylene carbonate. This protocol does not require external oxidants. It proceeded smoothly with good functional group tolerance and moderate to good yields.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01420G, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Hiroyoshi Takamura, Kosuke Hattori, Takumi Ohashi, Taichi Otsu, Isao Kadota
Stereodivergent synthesis of the C61–C74 and C69–C83 fragments of symbiodinolide elucidated the relative configuration of its C61–C83 fragment.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01312J, Communication

Pradeep Kumar, Deepanshi Saxena, Rahul Maitra, Sidharth Chopra, T. Narender
A simple and efficient protocol has been developed to access thioethers by reacting indoles with p-quinone methides using thiourea as a sulfur source.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01141K, Review Article

Vitaly A. Shcherbinin, Ekaterina R. Nasibullina, Elena Y. Mendogralo, Maxim G. Uchuskin
This review provides an updated outlook on the isolation of epoxyquinoids and an examination of their biological profile. Total, enantioselective synthesis, and the development of shorter approaches to construction of epoxyquinoids are addressed.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01040F, Paper

Hayeon Moon, Sunwoo Lee
Acyl pyrazoles, in the presence of B₂(OH)₄, efficiently yield amides when reacted with nitro compounds. The method is versatile, tolerates diverse functional groups, and holds promise for diverse organic molecule synthesis.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01317K, Communication

Yu Li, Mei Wang, Rongrong Ma, Rui Niu, Haodong Wang, Yantu Zhang, Jun-Bing Lin
A DABCO-catalyzed allylic alkylation of alkyne-substituted MBH carbonates with nitromethane was realized, delivering a series of all-carbon quaternary center-containing 1,4-enynes.
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Org. Biomol. Chem., 2023, Advance Article
DOI: 10.1039/D3OB01402A, Communication

Jiangkun Xiong, Maying Yan, Lvnan Jin, Weihong Song, Lei Xiao, Dong Xu, Chunyang Zhai, Douglas W. Stephan, Jing Guo
Organogermacycles are prepared in good to excellent yields by B(C₆F₅)₃ mediated domino hydrogermylation reaction of enones with dihydrogermanes.
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