Dithiocarbazate–Zn(II) complexes for photodynamic therapy and chemotherapy against lung cancer

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01777J, Research Article
JunGang Deng, YouRu Wu, AiLi Li, WeiPing Pan, LiXia Hou, DaQi Wu, ZhenLei Zhang, Feng Yang, Yi Gou
The Zn(II) complex could efficiently produce ˙O2 to damage lung cancer cells by photodynamic therapy. Simultaneously, the complex can cause cell damage by chemotherapy.
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Current progress in metal–organic frameworks and their derivatives for electrocatalytic water splitting

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01468A, Review Article
Yujung Chen, Peisen Liao, Kehan Jin, Yun Zheng, Huaiyu Shao, Guangqin Li
For electrocatalytic water splitting, MOFs can be optimized through structural modification, plane design and synergetic composite systems, and the annealing process further expands the types of MOF-based electrocatalytic materials.
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Synergetic microstructure engineering by induced ZB/WZ twin boundaries and S vacancies in a Zn0.5Cd0.5S-based S-scheme photocatalyst for highly efficient photocatalytic hydrogen production

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01187A, Research Article
Yuhao Zhang, Dingze Lu, Zhennan Wang, Min Zhou, Kiran Kumar Kondamareddy, Jing Li, Huiqing Fan, Dezhong Cao, Wingkei Ho
Development of structurally unique Zn0.5Cd0.5S (with twin structure and S vacancies) and a Zn0.5Cd0.5S-based metal–organic framework for photocatalytic applications.
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Structural confinement toward suppressing concentration and thermal quenching for improving near-infrared luminescence of Fe3+

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01649H, Research Article
Fangyi Zhao, Yuhe Shao, Zhen Song, Quanlin Liu
To enhance near-infrared luminescence, we introduce Fe3+ and Yb3+ ions to Sr9Ga(PO4)7 and utilize the structural confinement effect to selectively control energy transfer pathways so as to suppress luminescence concentration and thermal quenching.
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Manipulating pre-equilibria in olefin polymerization catalysis: backbone-stiffening converts a living into a highly active salan-type catalyst

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01537H, Research Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dmitry V. Uborsky, Mikhail I. Sharikov, Georgy P. Goryunov, Kristina M. Li, Anna Dall'Anese, Cristiano Zuccaccia, Antonio Vittoria, Teresa Iovine, Gianluigi Galasso, Christian Ehm, Alceo Macchioni, Vincenzo Busico, Alexander Z. Voskoboynikov, Roberta Cipullo
Stiffening the catalyst backbone of a slow salan-type catalyst converts it into a highly active indanosalan catalyst, producing highly isotactic PP with an activity rivalling the most productive known salan-catalyst, with much higher MW capability.
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Multi-interface engineering of NiS/Ni3S2/Fe3O4 nanoarchitectures for use as high-efficiency electrocatalysts toward the oxygen evolution reaction

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01563G, Research Article
Chengcheng Li, Anyang Bao, Cuizhen Yang, Guoqiang Liu, Xiang Chen, Mengyue Li, Yuwen Cheng, Dongming Liu
Multi-interfacial NiS/Ni3S2/Fe3O4 nanoarchitectures were designed and fabricated through chemical dealloying and a hydrothermal approach which exhibit a unique OER performance.
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The importance of second sphere interactions on single molecule magnet performance

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01634J, Review Article
Brodie E. Matheson, Tyson N. Dais, Marryllyn E. Donaldson, Gareth J. Rowlands, Paul G. Plieger
Secondary interactions occur beyond the primary coordination sphere and can influence the performance of single molecule magnets (SMMs). This article highlights the role that secondary interactions play in the synthesis and performance of SMMs.
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Self-promoted ammonia selectivity for the electro-reduction of nitrogen on gt-C3N4 supported single metal catalysts: the machine learning model and physical insights

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01390A, Research Article
Lifu Zhang, Lanlan Chen, Wanghui Zhao, Zhenpeng Hu, Jing Chen, Wenhua Zhang, Jinlong Yang
Intrinsic selectivity and activity correlation by machine learning for the nitrogen reduction reaction.
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Bi-directional strains increase the performance of Iridium oxide nanoparticles towards acidic oxygen evolution reaction in proton exchange membrane electrolyzers

Inorg. Chem. Front., 2023, Accepted Manuscript
DOI: 10.1039/D3QI01609A, Research Article
Xiao Wu, Shaoyun Hao, Yi He, Lecheng Lei, Xingwang Zhang
The challenge of achieving high performance for iridium-based catalysts towards oxygen evolution reaction (OER) in the proton exchange membrane (PEM) electrolyzers remains unsolved due to the highly acidic interface of...
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Reactivity variance between stereoisomers of saturated N-heterocyclic carbenes on gold surfaces

Inorg. Chem. Front., 2023, Advance Article
DOI: 10.1039/D3QI01541F, Research Article
Open Access Open Access
Gurkiran Kaur, Nathaniel L. Dominique, Gaohe Hu, Phattananawee Nalaoh, Rebekah L. Thimes, Shelby L. Strausser, Lasse Jensen, Jon P. Camden, David M. Jenkins
Two stereoisomers, one C2 symmetric and one Cs symmetric, of saturated N-heterocyclic carbenes (NHCs) were placed on gold films and they demonstrate different reactivity.
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