Stimuli-Cleavable Moiety Enabled Vinyl Polymer Degradation and Emerging Applications

Green Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3GC03086E, Tutorial Review
Jie Zheng, Zhuang Mao Png, Xian Chun Nicky Quek, Xian Jun Loh, Zibiao Li
Vinyl polymers have become ubiquitous products in our modern world, thanks to their exceptional strength, durability, and resistance to chemicals, all of which result from their highly stable all-carbon polymer...
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Co-SAC catalyzed utilization of methanol and ethanol in the transfer hydrogenation of azo bonds: experimental and theoretical studies

Green Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3GC02725B, Paper
Dibyajyoti Panja, Sadhan Dey, Rohini Saha, Rajib Sahu, Gourab Kanti Das, P. A. Bhobe, Sabuj Kundu
Transfer hydrogenation (TH) of non-polar bonds using methanol and ethanol as hydrogen source is a great challenge, and development of efficient 3d metal-based catalyst to accomplish such reactions is an...
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Mechanistic Investigation of a Ni-catalyzed electrochemical reductive cleavage of the α-o-4 bond in the lignin model compound benzyl phenyl ether

Green Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3GC01814H, Paper
Fang Lin, Predrag Petrovic, Ho-Yin TSE, Hanno Christian Erythropel, Jason Chun-Ho Lam, Paul Anastas
The electrochemical reductive cleavage of the C-O bond in the lignin α-O-4 model compound benzyl phenyl ether (BPE) at room temperature was investigated using earth-abundant nickel as a catalyst in...
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Novel benzimidazole-linked microporous conjugated polymers for highly selective adsorption and photocatalytic reduction of diluted CO2

Green Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3GC02966B, Paper
Wei Wu, Chunyuan Feng, Mantao Chen, Qin Tan, Yue Deng, Chao Zeng, Lixiang Zhong, Chunhui Dai
The intergated capture and photoreduction of diluted CO2 into energy-rich fuels represents an important challenge for renewable energy research and is attracting remarkable attention. In this study, two new benzimidazole-linked...
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Electrochemical cascade reactions: an account of the recent developments of the modern strategic tool in the arsenal of chemical synthesis

Green Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3GC01760E, Tutorial Review
Sushobhan Chowdhury, Manoj Kumar Yadav
In view of the growing demand for synthetic molecules or materials by researchers from both the core sciences and interdisciplinary sectors, the field of organic synthesis needs to be strategically...
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Halogen-bonding-mediated synthesis of amides and peptides

Green Chem., 2023, Advance Article
DOI: 10.1039/D3GC03102K, Paper
Mingqin Huang, Jun-Jie Li, Chi Zhang
We report the first methods for halogen-bonding-mediated formation of amide and peptide bonds. The methods can be used to synthesize not only amides but also dipeptides, tripeptides and pentapeptides in good to excellent yields without racemization.
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Electrochemically Grown Fe2O3/Fe3O4 Heterostructure Nanotubes with In2O3 induced Tandem Internal Electric Fields for Enhanced Photoelectrochemical Water Oxidation

Green Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3GC03466F, Paper
Xiaohui Yan, Gang Li, Kai Shen, Congwei Wang, Kaiying Wang
Nanostructured hematite (α-Fe2O3) shows promise as a semiconductor for photoelectrochemical (PEC) water oxidation. However, it suffers from inadequate charge separation, limited hole-collection efficiency and sluggish kinetics. Herein, nanotubular Fe2O3/Fe3O4 p-n...
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Decarboxylative [4 + 2] cycloaddition via ligand-to-metal charge transfer photoexcitation of a Cu-MOF

Green Chem., 2023, Advance Article
DOI: 10.1039/D3GC02639F, Paper
Wenjing Wang, Di Zeng, Juxue Wang, Bingkun Cui, Taikang Jia, Ruofan Li, Hongxiang Chu, Yu Zhang, Ling Zhang, Wenzhong Wang
Production of p-xylene (PX) via a broad biomass-derived furan cycloaddition has received incremental interest because of its renewable character.
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SnO2/CoS1.097 heterojunction as a green electrocatalyst for hydrogen evolution linking to assistant glycerol oxidation

Green Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3GC03534D, Paper
Xinjie Xie, Chunyong Zhang, Meng Xiang, Chengbin Yu, Wang-xi Fan, Shuang Dong, Zhou Yang
Hydrogen is green and sustainable energy, and water splitting is recognized as the most promising way to obtain hydrogen energy. At present, traditional electrocatalysts suffer from high cost and high...
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A Novel Approach for Synthesizing ɑ-Amino Acids via Formate Mediated Hydrogen Transfer and Carbon Source

Green Chem., 2023, Accepted Manuscript
DOI: 10.1039/D3GC02955G, Communication
Tian-Tian Zhao, Xu-Gang Zhang, Wen-Bo He, Peng-Fei Xu
Using a formate salt as a promising hydrogen carrier and one-carbon (C1) source, we have developed a novel and practical method for the preparation of α-amino acid derivatives under mild...
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