Faraday Discuss., 2023, 245,221-244
DOI: 10.1039/D3FD00015J, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Daniël B. Rap, Aude Simon, Kim Steenbakkers, Johanna G. M. Schrauwen, Britta Redlich, Sandra Brünken
Fragmentation pathways of benzonitrile and pyridine are elucidated using cryogenic infrared ion spectroscopy, quantum-chemical calculations and molecular dynamics simulations.
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Faraday Discuss., 2023, 245,446-466
DOI: 10.1039/D3FD00024A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Emily R. Ingman, Domantas Laurinavicius, Jin Zhang, Johanna G. M. Schrauwen, Britta Redlich, Jennifer A. Noble, Sergio Ioppolo, Martin R. S. McCoustra, Wendy A. Brown
Resonant excitation of CO and water-containing ices with a free-electron laser leads to CO photodesorption.
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Faraday Discuss., 2023, 245,164-180
DOI: 10.1039/D3FD00018D, Paper

Eleonora Bianchi, Ana López-Sepulcre, Cecilia Ceccarelli, Claudio Codella, Linda Podio, Mathilde Bouvier, Joan Enrique-Romero, Rafael Bachiller, Bertrand Lefloch
We analyse deuterated water (HDO) and sulfur dioxide (SO₂) at high-angular resolution in the binary system SVS13-A. We propose that molecular emission is produced by an accretion shock at the interface between the accretion streamer and the disk.
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Faraday Discuss., 2023, 245,609-619
DOI: 10.1039/D3FD00055A, Paper

Sascha T. Zeegers, Joan Mariñoso Guiu, Francisca Kemper, Jonathan P. Marshall, Stefan T. Bromley
Silicates are the main constituent of interstellar dust. Direct observations of nanometre-sized silicate grains would provide a smoking gun for the occurrence of grain condensation in the diffuse interstellar medium.
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Faraday Discuss., 2023, 245,261-283
DOI: 10.1039/D3FD00046J, Paper

Open Access

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Kevin M. Douglas, Lok Hin Desmond Li, Catherine Walsh, Julia H. Lehman, Mark A. Blitz, Dwayne E. Heard
The reaction of NH₂ and CH₃CHO becomes fast at low temperatures, and may be a potential source of CH₃CO radicals in the interstellar medium.
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Faraday Discuss., 2023, 245,298-308
DOI: 10.1039/D3FD00068K, Paper

Open Access

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Divita Gupta, Weslley G. D. P. Silva, José L. Doménech, Eline Plaar, Sven Thorwirth, Stephan Schlemmer, Oskar Asvany
The first rovibrational (IR) and rotational (mm-wave) spectra are measured for c-C₃H₂D⁺, a potential detection target in interstellar space.
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Faraday Discuss., 2023, 245,586-608
DOI: 10.1039/D3FD00039G, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Marie Van de Sande, Catherine Walsh, Tom J. Millar
The first AGB chemical kinetics model that includes porosity, dust–gas chemistry and companion UV photons, allows us to unravel the interplay of the complexities and identify suites of molecules to determine the presence of a companion star.
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Faraday Discuss., 2023, 245,327-351
DOI: 10.1039/D3FD00057E, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Nadia Balucani, Adriana Caracciolo, Gianmarco Vanuzzo, Dimitrios Skouteris, Marzio Rosi, Leonardo Pacifici, Piergiorgio Casavecchia, Kevin M. Hickson, Jean-Christophe Loison, Michel Dobrijevic
Low temperature kinetics, crossed beam experiments, calculations of the underlying potential energy surface and of the product branching fractions for the N(²D) + benzene reaction are reported. The results have been used in a photochemical model of Titan.
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Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00071K, Paper

Jinwen Liu, Limin Guo, Ye Xu, Jun Huang, Zhangquan Peng
This work identifies the key products and intermediates (O₂⁻, KO₂ and K₂O₂) and reveals their dependency on the electrode potential by combining in situ Raman spectroelectrochemistry and density functional theory calculations.
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Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00081H, Paper

Daniel Córdoba, Leandro N. Benavides, Daniel H. Murgida, Hernan B. Rodríguez, Ernesto J. Calvo
We have operando detected the formation of singlet oxygen in a real Li–O₂ battery by DMA fluorescence decay and its suppression by using physical quenchers, reaching an extended battery cycle life due to mitigation of spurious reactions
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