Transformations in crystals of DNA-functionalized nanoparticles by electrolytes

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00109A, Paper
Roger John-Erik Reinertsen, Felipe Jiménez-Ángeles, Sumit Kewalramani, Michael Bedzyk, Monica Olvera de la Cruz
Colloidal crystals of DNA-coated nanoparticles transition from face-centered cubic to body-centered cubic structures with increasing salinity; this transition is concurrent with salt-induced dehydration of the grafted DNA.
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Atomic-scale structure of interfacial water on gel and liquid phase lipid membranes

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00094J, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Simone Benaglia, Harriet Read, Laura Fumagalli
The molecular arrangement of interfacial water upon solid-to-liquid phase transition of lipid molecules was investigated with sub-molecular resolution by 3D AFM.
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A facile coprecipitation approach for synthesizing LaNi0.5Co0.5O3 as the cathode for a molten-salt lithium–oxygen battery

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00078H, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Qianyuan Qiu, Jiaqi Wang, Penghui Yao, Yongdan Li
The reaction pathway for Li2O generation on the surface of perovskite LaNi0.5Co0.5O3 for a molten-salt lithium–oxygen battery operating at 160 °C is presented.
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Hydrophobic hydration of the hydrocarbon adamantane in amorphous ice

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00102D, Paper
Open Access Open Access
Sukhpreet K. Talewar, Luis Carlos Pardo, Thomas F. Headen, Siriney O. Halukeerthi, Bharvi Chikani, Alexander Rosu-Finsen, Christoph G. Salzmann
The hydrophobic adamantane molecule is fully hydrated through vapour codeposition with water onto a cryogenic substrate and the structure of the first hydration shell is studied with neutron diffraction.
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Substrate effect on charging of electrified graphene/water interfaces

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00107E, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yongkang Wang, Yuki Nagata, Mischa Bonn
Surface-specific spectroscopy study of buried graphene electrodes, supported on different substrates, reveals that graphene charging is decoupled from the charging of its substrate. The substrate governs the reorganization of interfacial water.
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The accumulation of Li2CO3 in a Li–O2 battery with dual mediators

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00105A, Paper
Max Jenkins, Daniel Dewar, Tammy Nimmo, Chloe Chau, Xiangwen Gao, Peter G. Bruce
We examine the build-up and distribution of Li2CO3 within the porous gas diffusion electrode during cycling and its link to cell failure.
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The limit of macroscopic homogeneous ice nucleation at the nanoscale

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00099K, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
John A. Hayton, Michael B. Davies, Thomas F. Whale, Angelos Michaelides, Stephen J. Cox
We investigate the extent to which the size of the critical nucleus and the rate at which it grows in thin films of water are affected by the thickness of the film.
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A first-principles machine-learning force field for heterogeneous ice nucleation on microcline feldspar

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00100H, Paper
Pablo M. Piaggi, Annabella Selloni, Athanassios Z. Panagiotopoulos, Roberto Car, Pablo G. Debenedetti
A machine-learning force field paves the way for the simulation of heterogeneous ice nucleation on microcline from first principles.
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Collective modes and quantum effects in two-dimensional nanofluidic channels

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00115F, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Baptiste Coquinot, Maximilian Becker, Roland R. Netz, Lydéric Bocquet, Nikita Kavokine
This article introduces confined response functions, which provide a general framework for the Coulomb interactions of fluctuating matter in nanoscale confinement.
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Water–lipid interface in lipidic mesophases with excess water

Faraday Discuss., 2023, Advance Article
DOI: 10.1039/D3FD00118K, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yang Yao, Sara Catalini, Paolo Foggi, Raffaele Mezzenga
We study the influence of excess water on the phase transition of lipidic mesophases from the cubic to reverse hexagonal phase. Excess water permeates the interface and forms additional hydrogen bonds with lipids, accelerating the lipid dynamics.
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