Isonitrile μ2-carbido complexes

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Dalton Trans., 2023, 52,13906-13922
DOI: 10.1039/D3DT02649C, Paper
Liam K. Burt, Anthony F. Hill
A library of isonitrile ligated tungsten–platinum μ2-carbido complexes arise from the reactions of [WPt(μ2-C)Br(CO)2-(PPh3)2(Tp*)] (Tp* = tris(dimethylpyrazol-1-yl)borate) with selected isonitriles.
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Sandwich-type N-C@CoTe2@C anode: a stress-buffer nanostructure for stable sodium-ion storage

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Dalton Trans., 2023, 52,14003-14011
DOI: 10.1039/D3DT01831H, Paper
Lixiang Wang, Yahua Hu, Khak Ho Lim, Wei Zhang
A sandwich-structured electrode of dual-type carbon-confined CoTe2 nanocrystals was fabricated by using a biopolymer-cellulose template, enabling highly efficient and ultra-stable Na+ storage.
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Novel nitrogen-rich lanthanum nitrides induced by the ligand effect under pressure

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Dalton Trans., 2023, 52,14142-14150
DOI: 10.1039/D3DT01724A, Paper
Bo Jin, Yuanyuan Liu, Zhen Yao, Shuang Liu, Peng Wang
Unique tri-coordinated atoms with alternate sp2 and sp3 hybridizations are formed in the N18 ring of LaN8. The ligand effect of the introduced La atom on the N10 cage induces the structural evolution from Ī3m-N10 to Imm2-LaN10.
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Nickel-hydroxide-encapsulated polyacrylamide as a novel adsorptive composite for the capture of methylene blue from wastewater

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Dalton Trans., 2023, 52,14194-14209
DOI: 10.1039/D3DT02696E, Paper
A. Marey, Marzouk Adel, Ahmed M. A. El Naggar, Adel A. El-Zahhar, Mohamed H. Taha
Nickel hydroxide nanoparticles were used to encapsulate molecules of polyacrylamide to conserve the polymer because it is water-soluble. Therefore, a novel adsorptive composite is produced for utilization in the removal of MB dye from wastewater.
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Design, synthesis and reactivity of dimolybdenum complex bearing quaterphenylene-bridged pyridine-based PNP-type pincer ligand

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Dalton Trans., 2023, 52,14012-14016
DOI: 10.1039/D3DT02887A, Paper
Aya Eizawa, Kazuya Arashiba, Hiromasa Tanaka, Asuka Konomi, Kazunari Yoshizawa, Yoshiaki Nishibayashi
Dimolybdenum complexes bearing quaterphenylene-bridged PNP-type pincer ligand are designed and prepared according to DFT calculations on the cleavage step of dinitrogen-bridged dimolybdenum complexes bearing polyphenylene-bridged PNP ligands.
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H-atom site exchange in an iridium trans-dihydrogen/hydride complex, trans-[Ir(H)(η2-H2)(iPr)4(POCOP)(DMAP)]+

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Dalton Trans., 2023, 52,13858-13863
DOI: 10.1039/D3DT02366D, Communication
Nisha K. Agrawal, S. Gayathridevi, Soumya R. Dash, Kumar Vanka, Balaji R. Jagirdar
Treatment of trans-[Ir(H)(N)2(iPr)4(POCOP)(DMAP)][BAr4f] (2) with H2 (1 bar) under ambient conditions (298 K) results in the formation of a trans-[Ir(H)(η2-H2)(iPr)4(POCOP)(DMAP)][BAr4f] (3) complex. H-atom site exchange between the H2 and the hydride sites takes place in this complex.
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Integrating Co(OH)2 nanosheet arrays on graphene for efficient noble-metal-free EY-sensitized photocatalytic H2 evolution

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Dalton Trans., 2023, 52,13923-13929
DOI: 10.1039/D3DT02513F, Paper
Yu Wei, Jin-Ge Hao, Jia-Lin Zhang, Wei-Ya Huang, Shao-bo Ouyang, Kai Yang, Kang-Qiang Lu
A hierarchical hybrid cocatalyst is constructed by in situ anchoring Co(OH)2 nanosheet arrays on graphene. Using Eosin Y as a photosensitizer, the Co(OH)2-GR hybrid showed superior performance in photocatalytic H2 evolution.
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Structural variation, magnetism and single-source deposition of lanthanide-containing polyoxotitanates

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Dalton Trans., 2023, 52,14017-14026
DOI: 10.1039/D3DT02553E, Paper
Open Access Open Access
Rosa Müller, Olivia Georghiades, Joshua D. Bocarsly, Farheen N. Sayed, Víctor Riesgo-González, Andrew D. Bond, Clare P. Grey, Dominic S. Wright
Structurally versatile lanthanide-containing polyoxotitanates can be used as single-source precursors for the low-temperature synthesis of lanthanide–titanium hybrid oxides such as pyrochlores or brannerite.
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Flame doping of indium ions into TiO2 nanorod arrays for enhanced photochemical water oxidation

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Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02120C, Communication
Xue Chen, Biyi Chen, Dan Li, Longhua Li, Dongbo Xu, Weidong Shi
Indium (In) ions are diffused into TiO2 nanorod arrays on a FTO substrate via a flame doping method resulting in improved photoelectrochemical performance.
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