Enhancing supercapacitor performance using nanosheet-covered nanotube structures Co3S4/Ni0.96S@CNTs with carbon nanotubes as conductive substrates

Dalton Trans., 2023, 52,14047-14053
DOI: 10.1039/D3DT01792C, Paper
Yanmin Wang, Songtao Liu, Xuejiao Sun, Wenxiu He, Yongqiang Zhang
Transition metal sulfides have broad application prospects as supercapacitor electrode materials.
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Aurivillius-layered Bi2WO6 nanoplates with CoOx cocatalyst as high-performance piezocatalyst for hydrogen evolution

Dalton Trans., 2023, 52,14210-14219
DOI: 10.1039/D3DT02077K, Paper
Lining Tan, Xinran Sun, Jintao Zhang, Chengchao Jin, Fei Wang, Daiming Liu
In water with methanol (MeOH) as hole scavenger, the loading of CoOx cocatalysts can facilitate the transfer of holes from Bi2WO6 (BWO) to CoOx, which are then quickly consumed by MeOH, resulting in the boosted piezocatalytic HER efficiency.
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Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity

Dalton Trans., 2023, 52,13852-13857
DOI: 10.1039/D3DT02405A, Frontier
Nabeen K. Shrestha, Supriya A. Patil, Amol S. Salunke, Akbar I. Inamdar, Hyungsang Kim, Hyunsik Im
Metal-ion doping modulates electronic structure and coordination environment in MOFs, leading to partial exposure of metal nodes, thus enhancing the active sites, and accelerating the OER.
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Pure red-light emitting europium based complexes as efficient UV light converters: synthesis, crystal structure and photoluminescence properties

Dalton Trans., 2023, 52,14075-14087
DOI: 10.1039/D3DT01536J, Paper
Asgar Ali, Zubair Ahmed, Rahisuddin, K. Iftikhar
This paper reports three new crystallographically characterized Eu complexes, [Eu(fod)3(L)] (L = bzi, bath and py-im), and their photophysical properties in solution, solid state and PMMA thin films.
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Differential fluorescent response to amino acids based on metal–organic framework Zn-PBC

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02522E, Paper
Wenxin Lin, Yijia Wang, Haoke Zhang, Kei Hoi Shan, Panpan Si, Shijiang Yu, Zhen Wang, Dian Zhao, Junkuo Gao, Minghua Wu, Ben Zhong Tang
Zn-PBC, a metal-organic framework with ideal fluorescent property was prepared. It exhibited differential fluorescent response to different kinds of amino acids, which might provide a strategy to design MOF-based sensors for biomolecules in future.
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Hydrogen peroxide photo-fuel cells

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02518G, Frontier
Hiroaki Tada
H2O2-photofuel cell (PFC) is an important photoelectrochemical device contributing to the realization of a solar-driven clean energy cycle named the “hydrogen peroxide-keyed energy cycle” through combination with the photocatalytic H2O2 synthesis.
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Recent advances in the nanoarchitectonics of metal–organic frameworks for light-activated tumor therapy

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02725B, Perspective
Huijuan Duan, Fang Wang, Weizhe Xu, Gang Sheng, Zhaogang Sun, Hongqian Chu
The application of nMOFs to antitumor therapy, including drug delivery strategies, photodynamic therapy (PDT), photothermal therapy (PTT), and combination therapy, is presented.
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MnOxHy-modified CoMoP/NF nanosheet arrays as hydrogen evolution reaction and oxygen evolution reaction bifunctional catalysts under alkaline conditions

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02467A, Paper
Xuemin Wang, Ke Zhang, Yuhan Xie, Dehua Yu, Haoze Tian, Yongbing Lou
The nanosheet arrays of MnOxHy/CoMoP/NF exhibited exceptional hydrogen evolution reaction and oxygen evolution reaction activities.
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Metal coordination to solute binding proteins – exciting chemistry with potential biological meaning

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02417B, Paper
Kinga Garstka, Denise Bellotti, Joanna Wątły, Henryk Kozłowski, Maurizio Remelli, Magdalena Rowińska-Żyrek
ZnuA and AztC, solute binding proteins from Paracoccus denitrificans, bind Zn(II) and Ni(II) via their outercellular His-rich loop regions.
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Effects of oxygen functionalities on hydrous hydrazine decomposition over carbonaceous materials

Dalton Trans., 2023, Advance Article
DOI: 10.1039/D3DT02310A, Paper
Open Access Open Access
Silvio Bellomi, Ilaria Barlocco, Simone Tumiati, Patrizia Fumagalli, Nikolaos Dimitratos, Alberto Roldan, Alberto Villa
The structure-activity relationship of oxygen functionalities on carbon materials for the hydrazine decomposition reaction was elucidated by combining experiments and modelling, revealing carbon-oxygen double groups as active sites.
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