The role of dimensionality and direction of hydrogen-bonded networks in the mechanical flexibility of organic crystals

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00681F, Highlight
Binoy K. Saha, Sunirban Das, Ragima V. P. Veluthaparambath
The role of directionality and dimensionality of hydrogen-bonded synthons in the flexibility of organic crystals has been discussed.
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Cysteine-assisted overgrowth of gold nanorods to prepare highly branched gold nanoantennas with tunable morphological and plasmonic properties

CrystEngComm, 2023, 25,5486-5494
DOI: 10.1039/D3CE00685A, Paper
Cuixia Bi, Zhixiu Wang, Hongyan Zhao, Guangqiang Liu
In this work, gold nanoantennas with high branching properties were prepared by cysteine-assisted overgrowth of gold nanorods (AuNRs).
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Two flexible zinc–triazole–dicarboxylate frameworks: breathing behaviors for CO2 uptake and dye adsorption properties

CrystEngComm, 2023, 25,5174-5183
DOI: 10.1039/D3CE00787A, Paper
Yu-Jie Liang, Liu Liu, Jun Yao, Min Deng, Quan-Qing Xu, Ai-Xin Zhu, Bo Huang
Two flexible zinc–triazole–dicarboxylate frameworks exhibit breathing behaviors for CO2 uptake; however, they display distinct dye properties due to different framework charge and pore windows.
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Long-lived fluorinated boron-nitride dots exhibiting room-temperature phosphorescence and high-temperature resistance

CrystEngComm, 2023, 25,5533-5540
DOI: 10.1039/D3CE00286A, Paper
Xu Zhang, Shenghui Han, Gang Lian, Deliang Cui, Qilong Wang
A fluorination strategy was developed to prepare matrix-free F-BN nanodots, which exhibit extended RTP lifetime and resistance to high temperature.
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Substitution position regulating the excitation-dependent fluorescence–phosphorescence emission of formylphenylboronic acids for single-component white light and anticounterfeiting

CrystEngComm, 2023, 25,5479-5485
DOI: 10.1039/D3CE00725A, Paper
Guoyan Li, Xiaofeng Yang, Jinling Miao, Yu Cui, Guoxin Sun, Yexin Li
The substitution position has a drastic role in the room-temperature phosphorescence performance of three formylphenylboronic acid isomers, which further affects the excitation-dependent fluorescence–phosphorescence (ExDFPh) dual emission behavior.
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An Fe·MOF–Mo·POM hybrid material: a novel and efficient catalyst for selective benzyl alcohol oxidation to benzaldehyde

CrystEngComm, 2023, 25,5470-5478
DOI: 10.1039/D3CE00778B, Paper
Maryam Mohammadikish, Mahsa Panahi
Designing and synthesis of an efficient catalyst for the selective oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzCHO) is a significant method in green chemistry and catalysis.
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One-dimensional infinite chain Ag(I) complex with high quantum yield and TADF property: prepared by metal ion adjustment

CrystEngComm, 2023, 25,5405-5412
DOI: 10.1039/D3CE00764B, Paper
Zhen-Zhou Sun, Fu-Zhen Hu, Cheng-Jie Gao, Wen-Long Mou, Guo Wang, Ning Zhu, Xun Pan, Zhong-Feng Li, Hong-Liang Han, Hongbing Fu, Xiu-Lan Xin, Lixiong Dai, Qiong-Hua Jin, Qi-Ming Qiu
The complex AgDpq exhibits excellent photophysical properties and TADF characteristics than Cu(I) complex, which is related to the unique one-dimensional infinite chain structure and the smaller contribution of metal to the excited states.
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Halogen bonding in chloroiodates(III)

CrystEngComm, 2023, 25,5233-5237
DOI: 10.1039/D3CE00400G, Communication
Nikita A. Korobeynikov, Andrey N. Usoltsev, Maxim N. Sokolov, Alexander S. Novikov, Taisiya S. Sukhikh, Sergey A. Adonin
Oxidation of iodides of organic cations by dichlorine in aqueous HCl results in salts of tetrachloroiodate(III) [ICl4].
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Chalcogen bonding interactions in a series of aromatic selenocyanates

CrystEngComm, 2023, 25,5316-5323
DOI: 10.1039/D3CE00745F, Paper
Open Access Open Access
Jan Alfuth, Olivier Jeannin, Marc Fourmigué
Selenium atoms in aromatic selenocyanates exhibit two sizeable σ-holes, leading to recurrent supramolecular organizations with chalcogen-bonded (ChB) chain-like motifs and antiparallel arrangement of the chains through weaker ChB.
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Phosphorylated amelogenin N-terminal peptides regulate calcite crystal cluster formation in a water–acetonitrile system

CrystEngComm, 2023, 25,5150-5159
DOI: 10.1039/D3CE00165B, Paper
Wenwu Zou, Yutao Lin, Zhenze Xie, Yingxin Lin, Chang Du
The function of phosphorylated organic additives can be enhanced by changing the secondary structure of the organic matrix which may provide a new strategy for novel crystal synthesis.
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