Facile fabrication and characterization of rare earth complexes based on Keggin-type polyoxometalate with highly efficient activity for photocatalytic degradation of MO

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00746D, Paper
Ying-Yu Li, Guan-Yu Jin, Zhi-Qiang Wang, Cong Hu, Xue-Dong Wang, Jian-Ming Liu, Min Liu, Hong-Liang Han, Zhong-Feng Li, Qiong-Hua Jin
Rare earth complexes based on Keggin-type polyoxometalate for photocatalytic degradation of MO. The degradation rate reached more than 95% within 15 min.
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Highly varied reaction cavities within a single molecular crystal

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00714F, Paper
Michael R. Carr, Matthew Kochert, Wathsala L. I. Waduge, Gregory J. Deye, Kenneth W. Olsen, Jacob W. Ciszek
The various facets of a tetracene single crystal present highly varied reaction cavities at its surface, finally allowing for a systemic study of the cavities, which are critical to the reactivity in the solid phase.
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Joint effect of miscut r-plane sapphire substrate and different nucleation layers on structural characteristics of non-polar a-plane GaN films

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00478C, Paper
Ruiting Fang, Xiong Zhang, Shuchang Wang, Xuguang Luo, Shenyu Xu, Yifeng Xu, Zhiyi Lou, Lin Chen, Guohua Hu
High-quality non-polar a-plane GaN films are achieved with optimized miscut r-plane sapphire substrate and nucleation layers.
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Realizing luminescent from cuprous iodide complexes with high quantum yields by introducing planar aromatic groups and modification with halogen atoms on the ligand

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00815K, Paper
Abraham Mensah, Wei-Min Chen, Ennin Vendish Kweku, Peng-Lai Liu, Juan-Juan Shao, Fang-Ming Wang, Li-Zhuang Chen
Five novel AIO-structured cuprous iodide hybrid materials are prepared by introducing planar aromatic groups on the ligand DABCO. All the complexes have good stability, solubility, and high emission quantum yields (QYs) ranging from 70.3–95.3%.
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Study on the optical properties and electronic structures of Ba-doped KH2PO4 crystals

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00730H, Paper
Hao Hu, Wei Hong, Tingyu Liu, Longfeng Zhao, Jiachen Zhu
Electronic structure and one-dimensional configurational coordinate diagrams considering the electron–phonon coupling are derived to calculate the spectra.
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Optimised synthesis and further structural diversity of ytterbium benzene-1,4-dicarboxylate MOFs

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00865G, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas W. Chamberlain, Yasmine, Claire T. Coulthard, Guy J. Clarkson, Volkan Degirmenci, Yuni K. Krisnandi, Richard I. Walton
The synthesis of coordination polymers from a single metal cation and a bridging ligands with small changes in reaction conditions yields a set of distinct materials; their hydrothermal stability is related to their structural characteristics.
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Chemical vapour synthesis of carbon nano-onions filled with high-spin ferromagnetic γ-Fe50Ni50 nanocrystals: a structural and magnetic investigation

CrystEngComm, 2023, 25,5382-5386
DOI: 10.1039/D3CE00655G, Communication
Yini Liang, Aiqun Gu, Shanling Wang, Yi He, Shuping Zheng, Jian Guo, Filippo S. Boi
The recent discovery of an innovative chemical vapour synthesis (CVS) approach for the encapsulation and stabilization of high-spin ferromagnetic γ-Fe nanocrystals inside carbon nano-onions (CNOs) has attracted significant attention.
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Microdialysis on-chip crystallization of soluble and membrane proteins with the MicroCrys platform and in situ X-ray diffraction case studies

CrystEngComm, 2023, 25,5513-5523
DOI: 10.1039/D3CE00466J, Paper
Sofia Jaho, Yoann Sallaz-Damaz, Monika Budayova-Spano
The MicroCrys platform was developed to automate on-chip dialysis crystallization of proteins via chemical composition and temperature control, facilitating the optimization of crystallization conditions and the exploration of protein phase diagrams.
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Six novel multicomponent systems of theobromine with carboxylic acids: crystallographic structures, solubility determination and DFT calculations

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00762F, Paper
Xin-Yue Yuan, Yan Cheng, Jun Liu, Qi-Lei Sun, Fu-Min Xue
Cocrystals of theobromine with carboxylic acids prepared by ball milling and solution method: crystallographic structures and solubility determination.
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Hexnuclear, octanuclear, dodecanuclear, and hexadecnuclear polyoxomolybdenum(V)-based porous materials for selective adsorption of gases

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00736G, Paper
Rong-Yan Lin, Ru-Dan Dai, Xin Dong, Zhao-Hui Zhou
As the pH values decreased, triazole derivative assisted hexa-, octa-, hexadec- and dodeca-polynuclear molybdate-based porous complexes 1–4 are constructed successively. 1–4 have a good adsorption effect on O2 and CO2 respectively.
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