Dichlorosubstitution as a steering tool in hydrogen bonded cocrystals: the nature of rigid and flexible coformers in crystal structures

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00672G, Paper
Ritesh Dubey, Sandeep Singh
Dichlorosubstitution is utilized as a chemical probe to explore the landscape of phenol-pyridine based cocrystals.
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Kinetics or thermodynamics? Extolling their role to modulate the crystal phases and luminescence of KY3F10:Eu3+ powders

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00614J, Paper
Open Access Open Access
Pablo Serna-Gallén, Héctor Beltrán-Mir, Eloísa Cordoncillo
This study demonstrates the interplay between thermodynamics and kinetics in the transition-phase pathway and the isolation of specific KY3F10 polymorphs.
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Understanding of the difference in packing density of some energetic isomers

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00876B, Paper
Rong Wang, Yaoyao Linghu, Kai Zhong, Chaoyang Zhang
This work describes the underlying mechanism for the packing density differences in energetic isomers and presents a strategy for constructing high density energetic compounds.
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Crystallisation of organic hydrates by sublimation

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00732D, Paper
Open Access Open Access
Alexandra L. Volkwyn, Delia A. Haynes
Hydrates of organic molecules can be crystallised by sublimation if there is a strong hydrogen bond to water in the solid hydrate.
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NaCo7.38(PO4)4Cl4 in a series of homeotype compounds with stable cationic substructures derived from the sulphohalite archetype

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00819C, Paper
Olga Vsevolodovna Yakubovich, Galina Kiriukhina, Sergey Vladimirovich Simonov, Anatoly Volkov, Olga Dimitrova
In this paper, we present the synthesis and characterization of a Cl-bearing member of the phosphate family of compounds with a tetragonal crystal structure and similar topology in the basic...
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Synthesis, characterization and properties of new heat resistant energetic materials based on two C–C bridged pyrazole and benzene skeletons

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00530E, Paper
Rongzheng Zhang, Yuangang Xu, Feng Yang, Pengcheng Wang, Qiuhan Lin, Hui Huang, Ming Lu
C–C bridged pyrazole and benzene skeletons were used to design explosives 1c and 2c with high thermal stabilities, respectively.
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Melting pseudosymmetry and thermal expansion in 3-benzoylpropionic acid

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00940H, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tomasz Poręba, Marcin Świątkowski, Giorgia Confalonieri
3-Benzoylpropionic acid undergoes continuous transition associated with pseudosymmetry melting upon heating. The transition stems from a directional steric crowding, which refutes the recent premise of its colossal thermal expansion.
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Cation exchange in an anionic Metal-organic Framework enhancing propylene/propane separation

CrystEngComm, 2023, Accepted Manuscript
DOI: 10.1039/D3CE00761H, Paper
Xue Zhang, Huijuan Tang, Min Zeng, Rong Yang, Yu Wang, Kaijie Chen
Highly selective adsorptive separation of propylene/propane (C3H6/C3H8) using metal-organic frameworks (MOFs) is a promising approach to reducing energy consumption in the chemical industry. Here we report a 3D anionic MOF...
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Crystal engineering of a new pharmaceutical polymorph of gallic acid monohydrate: a structural comparative study and chemical computational quantum investigations

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00766A, Paper
Nasreddine Ghouari, Rim Benali-Cherif, Radhwane Takouachet, Wahiba Falek, Djallila Missaoui, Ali Rahmouni, El-Eulmi Bendeif, Nourredine Benali-Cherif
Exploiting new polymorphs of active pharmaceutical ingredients (APIs) has a significant role in the development of new processes for the pharmaceutical industry.
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Improving oxygen reduction reaction and oxygen evolution reaction activities with Ru–NiCo nanoparticles decorated on porous nitrogen-doped carbon for rechargeable Zn–air batteries and OER electrocatalysts

CrystEngComm, 2023, Advance Article
DOI: 10.1039/D3CE00693J, Paper
Lili Sui, Lihua Miao, Ye Kuang, Xiaoyan Shen, Dan Yang, He Huang
A series of nitrogen-doped carbon (CN) with NiCo alloys have been synthesized by pyrolyzing a simple bimetal zeolitic-imidazolate framework (ZIF) and further evenly loaded with metallic Ru nanoparticles to obtain Ru–NiCo/NC samples.
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