Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC04169G, Edge Article

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Tessa Keenan, Natasha E. Hatton, Jack Porter, Jean-Baptiste Vendeville, David E. Wheatley, Mattia Ghirardello, Alice. J. C. Wahart, Sanaz Ahmadipour, Julia Walton, M. Carmen Galan, Bruno Linclau, Gavin J. Miller, Martin A. Fascione
A carbohydrate phosphorylase is utilised in the synthesis of unnatural Manβ1,4-GlcNAc and longer β-mannan like glycans, including formation of phosphorolysis-stable thioglycoside linkages via novel "reverse thiophosphorylase" enzymatic activity.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC04542K, Edge Article

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David Tetzlaff, Tilo Rensch, Leonard Messing, Petra Banke, Sven Grätz, Daniel Siegmund, Lars Borchardt, Ulf-Peter Apfel
Utilizing carbon sources as milling additives for the direct mechanochemical one-pot synthesis of Fe₃Co₃Ni₃S₈/carbon (Pn/C) materials, employing elemental reaction mixtures to adjust overall physicochemical properties.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC04279K, Edge Article

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Baobao Chen, Chao Liu, Wei Cong, Fei Gao, Yan Zou, Li Su, Lei Liu, Alexander Hillisch, Lutz Lehmann, Donald Bierer, Xiang Li, Hong-Gang Hu
Cyclobutane-based conformationally constrained amino acids, termed E₇ and Z₇, were rationally designed and efficiently synthesized, and were used for RCM-mediated peptide stapling to afford E₇-E₇ geometry-specific stapled peptides.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03786J, Edge Article

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Jing Ren, Junhua Xu, Xiangxiang Kong, Jinlong Li, Kaizhi Li
The radical 1,2-difunctional alkylamidation of alkynes has been developed with the help of a bidentate coordinating group for the synthesis of β-alkylated enamides.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03153E, Edge Article

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Liang-Chun Lin, Tanner Smith, Qianxiang Ai, Brandon K. Rugg, Chad Risko, John E. Anthony, Niels H. Damrauer, Justin C. Johnson
The multiexciton quintet state, ⁵TT, generated as a singlet fission intermediate in pairs of molecular chromophores, is a promising candidate as a qubit or qudit in future quantum information science schemes.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03335J, Edge Article

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Sebastian Pflanze, Ruchira Mukherji, Anan Ibrahim, Markus Günther, Sebastian Götze, Somak Chowdhury, Lisa Reimer, Lars Regestein, Pierre Stallforth
Genome mining of the environmental bacterial isolate Pseudomonas nunensis 4A2e led to the discovery of three novel lipopeptides. Ecology-inspired bioassays highlight their importance in protecting the producing organism against various predators.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03797E, Edge Article

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Weijie Zhou, Suwen Chen, Yingjie Ouyang, Baoxuan Huang, Hongman Zhang, Weian Zhang, Jia Tian
A supramolecular platform was constructed for imaging-guided photodynamic and photothermal therapies by hypoxia tumour microenvironment remodeling via the inhibition of mitochondria-associated oxidative phosphorylation and combined therapeutic effects.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03508E, Edge Article

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Wenxuan Wei, Jun Wang, Xiaomei Kang, Haoquan Li, Qun He, Guanjun Chang, Weifeng Bu
The designed arylisocyanidorhodium(I) zwitterions 2 and 5 exhibit intense NIR-II phosphorescence, and their polymer nanoparticles were applied as bioimaging agents.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03892K, Edge Article

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Wei Zhang, Zhibin Zhao, Min Tan, Adila Adijiang, Shurong Zhong, Xiaona Xu, Tianran Zhao, Emusani Ramya, Lu Sun, Xueyan Zhao, Zhiqiang Fan, Dong Xiang
The conductance of molecular dynamic break junctions decreases upon an increased bias voltage. In contrast, the conductance of molecular fixed junctions increases upon an increased bias.
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03364C, Edge Article

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Tomohiro Fukushima, Soushi Yoshimitsu, Kei Murakoshi
The vibrational strong coupling of water molecules can induce the promotion of the charge transport of hydrated ions.
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