Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC03079B, Edge Article

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Tapas Kumar Maji, Rohan Jena, Subhajit Laha, Nimish Dwarkanath, Arpan Hazra, Ritesh Haldar, Sundaram Balasubramanian
Porous, supramolecular structures exhibit preferential encapsulation of guest molecules, primarily by the means of differences in the order of (noncovalent) interactions. The encapsulation preferences can be for geometry (dimension and...
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC03771A, Edge Article

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Tao Wang, Yuan-Yuan Zong, Tao Huang, Xiao-Ling Jin, Li-Zhu Wu, Qiang Liu
Site-selective and direct C–F bond functionalization of polyfluorinated iminosulfides was achieved to synthesize 3-fluoro-3-perfluoroalkyl-γ-lactams under photoredox-neutral conditions.
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Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC04532C, Edge Article

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Qianfeng Liu, Zhao YAN, Jianxin Gao, Hefei Fan, Min Li, Erdong Wang
In seawater, the severe hydroxide-based precipitation on the hydrogen evolution reaction (HER) electrode surface is still a major stumbling block for direct seawater electrolysis. Here, we design a direct seawater...
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC02773B, Edge Article

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Matthew A. Davis, Vivian Yaci Yu, Beverly Fu, Miao Wen, Edward J. Koleski, Joshua Silverman, Charles A. Berdan, Daniel K. Nomura, Michelle C. Y. Chang
In this work, we describe the engineering of a microbial platform to produce six different C₄ chemicals at near quantitative yields using a combination of metabolic engineering and directed evolution.
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Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC04119K, Edge Article

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Xiao-Jing Xie, Ying Wang, Qi-Yun Cao, Rajamani Krishna, Heng Zeng, Weigang Lu, Dan Li
Recently, examples of MOFs have been identified displaying ethane (C₂H₆) over ethylene (C₂H₄) adsorption selectivity. However, it remains a challenge to construct MOF materials with both large C₂H₆ adsorption capacity...
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC04727J, Edge Article

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Hang T. Dang, Arka Porey, Sachchida Nand, Ramon Trevino, Patrick Manning-Lorino, William B. Hughes, Seth O. Fremin, William T. Thompson, Shree Krishna Dhakal, Hadi D. Arman, Oleg V. Larionov
Sulfinamides can now be readily accessed from carboxylic acids and amines in a direct decarboxylative reaction enabled by the kinetically-driven reactivity of sulfinylamines and acridine photocatalysis.
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Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC04606K, Edge Article

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Hanyu Tu, Huaxin Liu, Laiqiang Xu, Zheng Luo, Lin Li, Ye Tian, Wentao Deng, Guoqiang Zou, Hongshuai Hou, Xiaobo Ji
Carbon dots (CDs) have attracted significant attention in the energy, environment, and biology fields due to their exceptional physicochemical properties. However, owing to the multifarious precursors and complex reaction mechanisms,...
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Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC02341A, Edge Article

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David Shultz, Paul D. Miller, Joshua Mengell, Martin Kirk, Lukasz Wojtas
A series of oligothiophene bis(dioxolene) complexes, SQ-Th_n-SQ (SQ = S = ½ Tp^Cum,MeZnII(3-tert-butyl-orthosemiquinonate); Tp^Cum,Me = tris(5-cumenyl-3-methylpyrazolyl)borate anion) have been synthesized, structurally characterized, and studied as a function of the number...
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Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC02515B, Edge Article

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Ved Vyas, Priyanka Maurya, Arindam Indra
N-alkylation of anilines by alcohols can be used as an efficient strategy to synthesise a wide range of secondary amines. In this respect, hydrogen borrowing methodology has been explored using...
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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC04006B, Edge Article

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Tongge Xu, Xiu Yin, Chunguang Zhai, Desi Chen, Xiaoying Yang, Shuhe Hu, Kuo Hu, Yuchen Shang, Jiajun Dong, Zhen Yao, Quanjun Li, Peng Wang, Ran Liu, Mingguang Yao, Bingbing Liu
A long range π-conjugation has been realized by the designed π–π interactions in phenanthrene/phenanthrene-based molecular crystals, forming the “transannular effect”, which can be amplified by high pressure and induce novel piezoluminescence.
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