Revealing the effect of LiOH on forming SEI by Co magnetic “probe”

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Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC04377K, Edge Article
Open Access Open Access
Zhiqiang Zhao, Wanneng Ye, Fengling Zhang, Yuanyuan Pan, Zengqing Zhuo, Feihu Zou, Xixiang Xu, Xiancheng Sang, Weiqi Song, Yue Zhao, Hongsen Li, Kuikui Wang, Chunfu Lin, Han Hu, Qinghao Li, Wanli Yang, Qiang Li
Solid-electrolyte-interphase (SEI) plays a critical role in lithium-ion batteries (LIBs) because of its important influence on electrochemical performance, such as cycle stability and coulombic efficiency, etc. Although LiOH has been...
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Parallel Kinetic Resolution of Aziridines via Chiral Phosphoric Acid-Catalyzed Apparent Hydrolytic Ring-Opening

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Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC03899H, Edge Article
Open Access Open Access
Juan Liu, Yi-Ying Du, Yu-Shi He, Yan Liang, Shangzhong Liu, Yiyi Li, Yi-Ming Cao
We report a chiral phosphoric acid-catalyzed apparent hydrolytic ring-opening reaction of racemic aziridines in a regiodivergent parallel kinetic resolution manner. Harnessing the acyloxy-assisted strategy, the highly stereocontrolled nucleophilic ring-opening of...
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The temperature-dependence of host–guest binding thermodynamics: experimental and simulation studies

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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC01975F, Edge Article
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Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laura M. Grimm, Jeffry Setiadi, Boryslav Tkachenko, Peter R. Schreiner, Michael K. Gilson, Frank Biedermann
Through isothermal titration calorimetry (ITC) and molecular dynamics (MD) simulations, we demonstrate that negative changes in heat capacity (ΔCp,b) are a unifying feature for both the classical and non-classical hydrophobic effect.
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Divergent 1,2-Carboallylation of Terminal Alkynes Enabled by Metallaphotoredox Catalysis with Switchable Triplet Energy Transfer

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Chem. Sci., 2023, Accepted Manuscript
DOI: 10.1039/D3SC04645A, Edge Article
Open Access Open Access
Jian Qin, Zhuzhu Zhang, Yi Lu, Shengqing Zhu, Lingling Chu
We report a metallaphotoredox strategy for stereodivergent three-component carboallylation of terminal alkynes with allylic carbonates and alkyl trifluoroborates. This redox-neutral dual catalytic protocol utilizes commercially available organic photocatalyst 4CzIPN and...
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A focus on penetration index – a new descriptor of chemical bonding

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Chem. Sci., 2023, Advance Article
DOI: 10.1039/D3SC90191B, Commentary
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Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wojciech Grochala
Electron clouds surrounding atoms interpenetrate in a molecule, due to weak van der Waals interactions or formation of a genuine chemical bond. Now, Alvarez and Echeverría have suggested a simple descriptor of how deep this interpenetration is, and called it a penetration index, i.
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