Dual-functional photocatalyst of CoSx/Cd0.7Zn0.3S without noble metals for efficient selective benzaldehyde synthesis coupled with H2 production

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY01162C, Paper
Xinan Chen, Jiaqi Yu, Zifan Zhang, Zizhong Zhang, Tao Ji, Wenyue Su
Dual-functional photocatalyst of CoSx/Cd0.7Zn0.3S without noble metals for efficient selective benzaldehyde synthesis coupled with H2 production.
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Examination of Pt2dba3 as a “cocktail”-type catalytic system for alkene and alkyne hydrosilylation reactions

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00865G, Paper
Evgeniia E. Ondar, Alexander Yu. Kostyukovich, Julia V. Burykina, Alexey S. Galushko, Valentine P. Ananikov
A simple approach aligned with dynamic catalysis principles was successfully applied in a study of hydrosilylation reactions. The readily available Pt2dba3 complex formed a “cocktail”-type system with comparable performance to known catalysts.
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N-Heterocyclic carbene-based porous polymer macroligand for the Ni-catalyzed C–H arylation of benzothiophenes

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY01263H, Communication
Open Access Open Access
Partha Samanta, Remi Beucher, Riddhi Kumari Riddhi, Alisa Ranscht, Florian M. Wisser, Elsje Alessandra Quadrelli, Jerome Canivet
A novel single-site Ni(NHC) catalyst embedded within a porous polymer has been developed for the heterogeneous direct C–H arylation of (benzo)thiophenes with unprecedented stability and recyclability.
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Computational modeling guided design of metal–organic frameworks for photocatalysis – a mini review

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00862B, Minireview
Sheng Yu, Qiaomin Wang, Jinglei Wang, Cong Fang, Yuanzhe Li, Jiankai Ge, Baizeng Fang
Metal–organic frameworks (MOFs) are porous materials used in photocatalysis. Their structure is optimized using computational modeling. This review emphasizes the role of computational design in enhancing MOF efficiency.
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Enhancing the performance for palladium catalysed tert-butyl hydroperoxide-mediated Wacker-type oxidation of alkenes

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY01046E, Paper
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthew N. Blair, Meadhbh Murray-Williams, Calum Maguire, Clare L. Brown, Qun Cao, Hongxin Chai, Yitong Li, Róisín L. O'Hagan, Paul Dingwall, Panagiotis Manesiotis, Catherine L. Lyall, John P. Lowe, Ulrich Hintermair, Peter C. Knipe, Mark J. Muldoon
This work examines the palladium(II) catalysed oxidation of terminal alkenes to their corresponding methyl ketones using tert-butyl hydroperoxide (TBHP) as the oxidant.
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Carbon-supported Co/Co3O4 hybrid catalyst: an efficient non-noble metal catalyst for the hydrodeoxygenation of vanillin

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00971H, Paper
Zhihua Zhu, Chaochong Zhang, Peng Zhou, Bo Han, Zehui Zhang, Bing Liu
Developing Co-based catalysts with high efficiency and low cost is significant for the efficient hydrodeoxygenation of biomass-derived vanillin to 2-methoxy-4-methylphenol (MMP).
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Methane monooxygenases; physiology, biochemistry and structure

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00737E, Review Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yasuyoshi Sakai, Hiroya Yurimoto, Seigo Shima
Methane monooxygenases (MMOs) are potential biocatalysts for industrial methanol production from methane. We summarize recent structural and biochemical studies of pMMO and discuss the future directions to develop efficient and robust biocatalysts.
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Natural alternative heme-environments allow efficient peroxygenase activity by cytochrome P450 monooxygenases

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY01207G, Paper
Open Access Open Access
Ana C. Ebrecht, Martha S. Smit, Diederik J. Opperman
Mild oxyfunctionalization reactions driven by hydrogen peroxide using cytochrome P450 monooxygenases with alternative heme environments.
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Tuning the active sites and optimizing the d-spacing value in CoFe-LDH by ex situ intercalation of guest anions: an innovative electrocatalyst for overall water splitting reaction

Catal. Sci. Technol., 2023, Advance Article
DOI: 10.1039/D3CY00859B, Paper
Sreenivasan Nagappan, Arun Karmakar, Ragunath Madhu, Hariharan N. Dhandapani, Suprobhat Singha Roy, Subrata Kundu
A facile strategy of ex situ guest anion incorporation into CoFe-LDH has been developed, in which the guest anion with the optimized concentration greatly enhances the OER, HER and total water splitting performance of the CoFe-LDH.
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Construction of core-shell MOF@COF hybrids with Z-scheme heterojunction for efficient visible light photocatalysis

Catal. Sci. Technol., 2023, Accepted Manuscript
DOI: 10.1039/D3CY00869J, Paper
Jun Pang, Weijie Chen, Jintao Hu, Jie Cheng, Mingqiang Tang, Zewei Liu, Rong Tan
Metal-organic frameworks (MOFs) have emerged as promising photocatalysts due to their tunable architectures and semiconductor-like behavior. However, their photocatalytic efficiency is often hampered by suboptimal light utilization and fast charge...
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