Recent advances in cross-coupling of alcohols via borrowing hydrogen catalysis

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00003J, Feature Article
Suteerna Mullick, Adrija Ghosh, Debasis Banerjee
This article highlights the recent advances and significance of β-alkylation reactions towards the synthesis of higher order alcohols.
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Redox-neutral zinc-catalyzed cascade [1,4]-H shift/annulation of diaziridines with donor–acceptor aziridines

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00226A, Communication
Swati Samantaray, Prabhat Kumar Maharana, Subhradeep Kar, Sharajit Saha, Tharmalingam Punniyamurthy
A Zn(II)-catalyzed (3+2)-annulation of diaziridines with DA aziridines has been accomplished via 1,4-hydride shift to furnish imidazo[1,5-b]pyrazole-4,4-dicarboxylates under mild reaction conditions.
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A solvent-controlled photoresponsive ionic hydrogen-bonded organic framework for encryption applications

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00701H, Communication
Ming-Feng Huang, Li-Hui Cao, Bin Zhou
An ionic hydrogen-bonded organic framework exhibits fast and reversible photochromic properties. Benefiting from the stimuli-responsive property, information encryptions and decryptions integrated with photoresponsivity are successfully designed.
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Small-size and well-dispersed Fe nanoparticles embedded in carbon rods for efficient oxygen reduction reaction

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00119B, Communication
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xinde Duan, Fayuan Ge, Yang Liu, Hegen Zheng
Using a “vapor adsorption” strategy, uniform carbon-protected metal (Fe and Zn) NPs (7 nm) have been successfully prepared. Significantly, this catalyst exhibits wonderful ORR activity in 0.1 M KOH and much better E1/2 of 0.868 V (vs. RHE).
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AI in computational chemistry through the lens of a decade-long journey

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00010B, Feature Article
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pavlo O. Dral
AI-enhanced computational chemistry methods such as AIQM1 break through the limitations of the traditional quantum chemistry.
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Enantioselective synthesis of tricyclic oxoquinolines via NHC-catalyzed Michael-aldol-lactamization-dehydration cascade

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00502C, Communication
Shilpa Barik, Ganga Sankar, Akkattu T. Biju
NHC-catalyzed cascade reaction of enals with malonates bearing a 2-aminophenyl group leading to the enantioselective synthesis of tricyclic oxoquinolines via the chiral α,β-unsaturated acylazoliums is presented.
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Fluorescent metal nanoclusters: prospects for photoinduced electron transfer and energy harvesting

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00021H, Feature Article
Soumyadip Bhunia, Manish Mukherjee, Pradipta Purkayastha
Research on noble metal nanoclusters (MNCs) (elements with filled electron d-bands) is progressing forward because of the extensive and extraordinary chemical, optical, and physical properties of these materials.
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A multicomponent triformylphoroglucinol-based covalent organic framework for overall hydrogen peroxide photosynthesis

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00511B, Communication
Erchong Chai, Lanting Huang, Lei Jiao, Zhiwei Xiao, Xiang Zhang, Yaobing Wang
A multicomponent covalent organic framework (COF-Tfp-BpyDaaq) integrating bipyridine with diaminoanthraquinone through a triformylphoroglucinol linkage was synthesized for the first time as a photocatalyst for overall H2O2 photosynthesis.
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Anti-proliferative, -migratory and -clonogenic effects of long-lasting nitric oxide release in HepG2 cells

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00232F, Communication
Rakhi Bormon, Ekta Srivastava, Rafat Ali, Prerna Singh, Ashok Kumar, Sandeep Verma
We have synthesized 6,9-disubstituted purines that exhibit sustained release of nitric oxide in the presence of glutathione, displaying significant anticancer properties in HepG2 cells.
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Synthesis of sydnonimines from sydnones and their use for bioorthogonal release of isocyanates in cells

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC00490F, Communication
Open Access Open Access
Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Judith Baudet, Emilie Lesur, Maxime Ribéraud, Arnaud Chevalier, Timothée D’Anfray, Pierre Thuéry, Davide Audisio, Frédéric Taran
A new synthetic route to sydnonimines allows the preparation of probes to release isocyanates inside living cells.
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